TY - JOUR
T1 - X-ray crystal structure of a molybdenum complex with both end-on hydrazido(2-)- and side-on hydrazido(1 - )-ligands
AU - Chatt, Joseph
AU - Dilworth, Jonathan R.
AU - Dahlstrom, Phillip L.
AU - Zubieta, Jon
PY - 1980
Y1 - 1980
N2 - The bis[hydrazido(2 - )]-complex [Mo-(NNMePh)2(S 2CNMe2)2] reacts with 1 equiv. of HCl to give [Mo(NNMePh)(NHNMePh)(S2CNME2)2]+, isolated as the tetraphenylborate salt, an X-ray crystal structure determination of which shows that the complex is seven-co-ordinate, displaying both end-on hydrazido-(2 - )- and side-on hydrazido(1 - )-co-ordination; the N-N distance in the hydrazido (2 - )-ligand of 1.29 Å is close to that observed in the bis[hydrazido(2 - )]-precursor, and the hydrazido(1 - )-ligand is asymmetrically side-on bound with metal-nitrogen distances of 2.07 and 2.18 Å and an N-N distance of 1.39 Å.
AB - The bis[hydrazido(2 - )]-complex [Mo-(NNMePh)2(S 2CNMe2)2] reacts with 1 equiv. of HCl to give [Mo(NNMePh)(NHNMePh)(S2CNME2)2]+, isolated as the tetraphenylborate salt, an X-ray crystal structure determination of which shows that the complex is seven-co-ordinate, displaying both end-on hydrazido-(2 - )- and side-on hydrazido(1 - )-co-ordination; the N-N distance in the hydrazido (2 - )-ligand of 1.29 Å is close to that observed in the bis[hydrazido(2 - )]-precursor, and the hydrazido(1 - )-ligand is asymmetrically side-on bound with metal-nitrogen distances of 2.07 and 2.18 Å and an N-N distance of 1.39 Å.
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U2 - 10.1039/C39800000786
DO - 10.1039/C39800000786
M3 - Article
AN - SCOPUS:37049097287
SN - 0022-4936
SP - 786
EP - 787
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 16
ER -