When VSEPR fails: Experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides

Marites A. Guino-O; Jacob S. Alexander; Michael L. McKee; Håkon Hope; Ulrich B. Englich; Karin Ruhlandt-Senge

doi:10.1002/chem.200901538

When VSEPR fails: Experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides

Marites A. Guino-O, Jacob S. Alexander, Michael L. McKee, Håkon Hope, Ulrich B. Englich, Karin Ruhlandt-Senge

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24 Scopus citations

Abstract

The synthesis, structural, and spectral characterization as well as a theoretical study of a family of alkaline-earth-metal acetylides provides insights into synthetic access and the structural and bonding characteristics of this group of highly reactive compounds. Based on our earlier communication that reported unusual geometry for a family of triphenylsilyl-substituted alkaline-earth-metal acetylides, we herein present our studies on an expanded family of target derivatives, providing experimental and theoretical data to offer new insights into the intensively debated theme of structural chemistry in heavy alkaline-earth-metal chemistry.

Original language	English (US)
Pages (from-to)	11842-11852
Number of pages	11
Journal	Chemistry - A European Journal
Volume	15
Issue number	44
DOIs	https://doi.org/10.1002/chem.200901538
State	Published - 2009

Keywords

Acetylides
Alkaline earth metals
Secondary interactions
Structure elucidation
Structure-determining factors

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.200901538

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When VSEPR fails : Experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides. / Guino-O, Marites A.; Alexander, Jacob S.; McKee, Michael L.; Hope, Håkon; Englich, Ulrich B.; Ruhlandt-Senge, Karin.

In: Chemistry - A European Journal, Vol. 15, No. 44, 2009, p. 11842-11852.

Research output: Contribution to journal › Article › peer-review

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AU - Englich, Ulrich B.

AU - Ruhlandt-Senge, Karin

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KW - Alkaline earth metals

KW - Secondary interactions

KW - Structure elucidation

KW - Structure-determining factors

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When VSEPR fails: Experimental and theoretical investigations of the behavior of alkaline-earth-metal acetylides

Abstract

Keywords

ASJC Scopus subject areas

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