Variations on a one-dimensional theme in the copper-diphosphonatoalkane system: The structures of [Cu2(bisterpy){HO3P(CH 2)2PO3H}2] • xH2O (x = 0 and 6), [Cu2(bisterpy)(H2O)2{HO 3P(CH2)2PO3H}](NO3) 2

Bon Kweon Koo; Eric Burkholder; N. Gabriel Armatas; Jon Zubieta

doi:10.1016/j.ica.2005.06.010

Variations on a one-dimensional theme in the copper-diphosphonatoalkane system: The structures of [Cu₂(bisterpy){HO₃P(CH ₂)₂PO₃H}₂] • xH₂O (x = 0 and 6), [Cu₂(bisterpy)(H₂O)₂{HO ₃P(CH₂)₂PO₃H}](NO₃) ₂

Bon Kweon Koo, Eric Burkholder, N. Gabriel Armatas, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The hydrothermal reactions of a Cu(II) source, bisterpy, and an organodiphosphonate yield a family of one-dimensional materials: [Cu ₂(bisterpy){HO₃P(CH₂)₂PO ₃H}₂] (1), [Cu₂(bisterpy){HO ₃P(CH₂)₂PO₃H}₂] • 6H₂O (2 • 6H₂O), [Cu₂(bisterpy)(H ₂O)₂{HO₃P(CH₂)₂PO ₃H}](NO₃)₂ (3), and [Cu₂(bisterpy) (NO₃)₂{HO₃P(CH₂)₃PO ₃H}] • 2H₂O (4 • 2H₂O). In all cases, axially distorted '4 + 1' Cu(II) square pyramids are linked through dipodal bisterpy and diphosphonate rods into the chain structures. However, the variability in the apical ligand of the copper results in considerable structural variability within the common one-dimensional theme. The one-dimensional Cu(II)/bisterpy/organodiphosphonate structure is also observed as an embedded subunit in the two-dimensional [Cu₂(bisterpy)(H ₂O)₂(H₄Mo₄O₁₄){O ₃P(CH₂)₂PO₃}] (5) where the unusual, neutral polyoxomolybdate {H₄Mo₄O₁₄} serves to crosslink these chains into a network structure.

Original language	English (US)
Pages (from-to)	3865-3872
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	358
Issue number	13
DOIs	https://doi.org/10.1016/j.ica.2005.06.010
State	Published - Sep 1 2005

Keywords

Copper-bisterpy
Copper-diphosphonates
Copper-molybdate
Hydrothermal synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2005.06.010

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Variations on a one-dimensional theme in the copper-diphosphonatoalkane system: The structures of [Cu₂(bisterpy){HO₃P(CH ₂)₂PO₃H}₂] • xH₂O (x = 0 and 6), [Cu₂(bisterpy)(H₂O)₂{HO ₃P(CH₂)₂PO₃H}](NO₃) ₂. / Koo, Bon Kweon; Burkholder, Eric; Armatas, N. Gabriel et al.
In: Inorganica Chimica Acta, Vol. 358, No. 13, 01.09.2005, p. 3865-3872.

Research output: Contribution to journal › Article › peer-review

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title = "Variations on a one-dimensional theme in the copper-diphosphonatoalkane system: The structures of [Cu2(bisterpy){HO3P(CH 2)2PO3H}2] • xH2O (x = 0 and 6), [Cu2(bisterpy)(H2O)2{HO 3P(CH2)2PO3H}](NO3) 2",

abstract = "The hydrothermal reactions of a Cu(II) source, bisterpy, and an organodiphosphonate yield a family of one-dimensional materials: [Cu 2(bisterpy){HO3P(CH2)2PO 3H}2] (1), [Cu2(bisterpy){HO 3P(CH2)2PO3H}2] • 6H2O (2 • 6H2O), [Cu2(bisterpy)(H 2O)2{HO3P(CH2)2PO 3H}](NO3)2 (3), and [Cu2(bisterpy) (NO3)2{HO3P(CH2)3PO 3H}] • 2H2O (4 • 2H2O). In all cases, axially distorted '4 + 1' Cu(II) square pyramids are linked through dipodal bisterpy and diphosphonate rods into the chain structures. However, the variability in the apical ligand of the copper results in considerable structural variability within the common one-dimensional theme. The one-dimensional Cu(II)/bisterpy/organodiphosphonate structure is also observed as an embedded subunit in the two-dimensional [Cu2(bisterpy)(H 2O)2(H4Mo4O14){O 3P(CH2)2PO3}] (5) where the unusual, neutral polyoxomolybdate {H4Mo4O14} serves to crosslink these chains into a network structure.",

keywords = "Copper-bisterpy, Copper-diphosphonates, Copper-molybdate, Hydrothermal synthesis",

author = "Koo, {Bon Kweon} and Eric Burkholder and Armatas, {N. Gabriel} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0242153. ",

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T1 - Variations on a one-dimensional theme in the copper-diphosphonatoalkane system

T2 - The structures of [Cu2(bisterpy){HO3P(CH 2)2PO3H}2] • xH2O (x = 0 and 6), [Cu2(bisterpy)(H2O)2{HO 3P(CH2)2PO3H}](NO3) 2

AU - Koo, Bon Kweon

AU - Burkholder, Eric

AU - Armatas, N. Gabriel

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0242153.

PY - 2005/9/1

Y1 - 2005/9/1

N2 - The hydrothermal reactions of a Cu(II) source, bisterpy, and an organodiphosphonate yield a family of one-dimensional materials: [Cu 2(bisterpy){HO3P(CH2)2PO 3H}2] (1), [Cu2(bisterpy){HO 3P(CH2)2PO3H}2] • 6H2O (2 • 6H2O), [Cu2(bisterpy)(H 2O)2{HO3P(CH2)2PO 3H}](NO3)2 (3), and [Cu2(bisterpy) (NO3)2{HO3P(CH2)3PO 3H}] • 2H2O (4 • 2H2O). In all cases, axially distorted '4 + 1' Cu(II) square pyramids are linked through dipodal bisterpy and diphosphonate rods into the chain structures. However, the variability in the apical ligand of the copper results in considerable structural variability within the common one-dimensional theme. The one-dimensional Cu(II)/bisterpy/organodiphosphonate structure is also observed as an embedded subunit in the two-dimensional [Cu2(bisterpy)(H 2O)2(H4Mo4O14){O 3P(CH2)2PO3}] (5) where the unusual, neutral polyoxomolybdate {H4Mo4O14} serves to crosslink these chains into a network structure.

AB - The hydrothermal reactions of a Cu(II) source, bisterpy, and an organodiphosphonate yield a family of one-dimensional materials: [Cu 2(bisterpy){HO3P(CH2)2PO 3H}2] (1), [Cu2(bisterpy){HO 3P(CH2)2PO3H}2] • 6H2O (2 • 6H2O), [Cu2(bisterpy)(H 2O)2{HO3P(CH2)2PO 3H}](NO3)2 (3), and [Cu2(bisterpy) (NO3)2{HO3P(CH2)3PO 3H}] • 2H2O (4 • 2H2O). In all cases, axially distorted '4 + 1' Cu(II) square pyramids are linked through dipodal bisterpy and diphosphonate rods into the chain structures. However, the variability in the apical ligand of the copper results in considerable structural variability within the common one-dimensional theme. The one-dimensional Cu(II)/bisterpy/organodiphosphonate structure is also observed as an embedded subunit in the two-dimensional [Cu2(bisterpy)(H 2O)2(H4Mo4O14){O 3P(CH2)2PO3}] (5) where the unusual, neutral polyoxomolybdate {H4Mo4O14} serves to crosslink these chains into a network structure.

KW - Copper-bisterpy

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KW - Copper-molybdate

KW - Hydrothermal synthesis

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