Use of Laser-Directed Chemical Vapor Deposition to Fabricate Durable, Optically Transparent, Platinum Thin Film Electrodes

Dan Rooney; D. Negrotti; T. Byassee; D. Macero; J. Chaiken; B. Vastag

doi:10.1149/1.2086620

Use of Laser-Directed Chemical Vapor Deposition to Fabricate Durable, Optically Transparent, Platinum Thin Film Electrodes

Dan Rooney, D. Negrotti, T. Byassee, D. Macero, J. Chaiken, B. Vastag

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

We report on the use of a novel organometallic precursor for laser-directed chemical vapor deposition of platinum films. We demonstrate their optical transparency and their bulk-platinum-like electrochemical response. The effects of moderate temperature annealing in oxygen and electrochemical cycling in H₂SO₄ on their electrochemical and optical properties are related. Based on the appearance of scanning electron micrographs and their enhanced transparency, these films would seem to be similar to those produced by photoelectrodeposition.

Original language	English (US)
Pages (from-to)	1162-1166
Number of pages	5
Journal	Journal of the Electrochemical Society
Volume	137
Issue number	4
DOIs	https://doi.org/10.1149/1.2086620
State	Published - Apr 1990

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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10.1149/1.2086620

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abstract = "We report on the use of a novel organometallic precursor for laser-directed chemical vapor deposition of platinum films. We demonstrate their optical transparency and their bulk-platinum-like electrochemical response. The effects of moderate temperature annealing in oxygen and electrochemical cycling in H2SO4 on their electrochemical and optical properties are related. Based on the appearance of scanning electron micrographs and their enhanced transparency, these films would seem to be similar to those produced by photoelectrodeposition.",

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AU - Negrotti, D.

AU - Byassee, T.

AU - Macero, D.

AU - Chaiken, J.

AU - Vastag, B.

PY - 1990/4

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N2 - We report on the use of a novel organometallic precursor for laser-directed chemical vapor deposition of platinum films. We demonstrate their optical transparency and their bulk-platinum-like electrochemical response. The effects of moderate temperature annealing in oxygen and electrochemical cycling in H2SO4 on their electrochemical and optical properties are related. Based on the appearance of scanning electron micrographs and their enhanced transparency, these films would seem to be similar to those produced by photoelectrodeposition.

AB - We report on the use of a novel organometallic precursor for laser-directed chemical vapor deposition of platinum films. We demonstrate their optical transparency and their bulk-platinum-like electrochemical response. The effects of moderate temperature annealing in oxygen and electrochemical cycling in H2SO4 on their electrochemical and optical properties are related. Based on the appearance of scanning electron micrographs and their enhanced transparency, these films would seem to be similar to those produced by photoelectrodeposition.

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Use of Laser-Directed Chemical Vapor Deposition to Fabricate Durable, Optically Transparent, Platinum Thin Film Electrodes

Abstract

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