Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex

Eric Burkholder; Fenton Heirtzler; Laura Orian; Wayne Ouellette; Jon Zubieta

doi:10.1016/j.poly.2008.09.007

Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex

Eric Burkholder, Fenton Heirtzler, Laura Orian, Wayne Ouellette, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Hydrothermal treatment of 2,3-bis(2′,6″-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2′-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.

Original language	English (US)
Pages (from-to)	3700-3702
Number of pages	3
Journal	Polyhedron
Volume	27
Issue number	18
DOIs	https://doi.org/10.1016/j.poly.2008.09.007
State	Published - Dec 12 2008

Keywords

Copper
Hydrothermal
Macrocycle
Molybdenum
Structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2008.09.007

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title = "Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex",

abstract = "Hydrothermal treatment of 2,3-bis(2′,6″-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2′-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.",

keywords = "Copper, Hydrothermal, Macrocycle, Molybdenum, Structure",

author = "Eric Burkholder and Fenton Heirtzler and Laura Orian and Wayne Ouellette and Jon Zubieta",

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doi = "10.1016/j.poly.2008.09.007",

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T1 - Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex

AU - Burkholder, Eric

AU - Heirtzler, Fenton

AU - Orian, Laura

AU - Ouellette, Wayne

AU - Zubieta, Jon

PY - 2008/12/12

Y1 - 2008/12/12

N2 - Hydrothermal treatment of 2,3-bis(2′,6″-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2′-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.

AB - Hydrothermal treatment of 2,3-bis(2′,6″-bipyridyl)quinoxaline, molybdenum trioxide, cupric acetate and water unexpectedly forms the Cu(II) complex of a planar, macrocyclic 2-acyl-6,2′-bipyridyl dimer, imbedded within a copper benzotrizolate-octamolybtate matrix. X-ray crystallographic characterization of this material, and scalar relativistic ZORA DFT modeling of the complex dication are presented.

KW - Copper

KW - Hydrothermal

KW - Macrocycle

KW - Molybdenum

KW - Structure

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DO - 10.1016/j.poly.2008.09.007

M3 - Article

AN - SCOPUS:56349169392

SN - 0277-5387

VL - 27

SP - 3700

EP - 3702

JO - Polyhedron

JF - Polyhedron

IS - 18

ER -

Unusual hydrothermal synthesis of a heteroaromatic macrocyclic complex

Abstract

Keywords

ASJC Scopus subject areas

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