TY - JOUR
T1 - Tungsten-organoimido chemistry. The crystal and molecular structures of [(n-C4H9)4N][W(NC6H4CH3)Cl5] and [(n-C4H9)4N][C7H7NH3][W2OCl8(NC6H4CH3)2]
AU - Qin, Chen
AU - McClinton, Deborah
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the National Science Foundation (CHE8815299).
PY - 1992/5/15
Y1 - 1992/5/15
N2 - The reaction of [(n-C4H9)4N]4[H3PW11O39] with [W(NC5H4CH3)Cl4]2 yields a mixture of [(n-C4H9)4N][W(NC6H4CH3)Cl5] (1) and [(n-C4H9)4N][C7H7NH3][W2OCl8(NC6H4CH3)2] (2). Crystal data: 1, monoclinic space group P21/c, a=10.950(2), b=11.254(3), c=12.920 Å, β=108.96(2)°, V=1506.0(6) Å3, Z=2, Dcalc=1.56 g cm-3, solution and refinement based on 2190 reflections converged at a conventional discrepancy value of 0.069; 2, monoclinic space group P21/c, a=14.001(8), b=26.68(1), c=15.278(9) Å, β=104.28(4)°, V=5534(3) Å3, Z=4, Dcalc=1.47 g cm-3, 4187 reflections, R=0.069.
AB - The reaction of [(n-C4H9)4N]4[H3PW11O39] with [W(NC5H4CH3)Cl4]2 yields a mixture of [(n-C4H9)4N][W(NC6H4CH3)Cl5] (1) and [(n-C4H9)4N][C7H7NH3][W2OCl8(NC6H4CH3)2] (2). Crystal data: 1, monoclinic space group P21/c, a=10.950(2), b=11.254(3), c=12.920 Å, β=108.96(2)°, V=1506.0(6) Å3, Z=2, Dcalc=1.56 g cm-3, solution and refinement based on 2190 reflections converged at a conventional discrepancy value of 0.069; 2, monoclinic space group P21/c, a=14.001(8), b=26.68(1), c=15.278(9) Å, β=104.28(4)°, V=5534(3) Å3, Z=4, Dcalc=1.47 g cm-3, 4187 reflections, R=0.069.
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U2 - 10.1016/S0020-1693(00)85308-6
DO - 10.1016/S0020-1693(00)85308-6
M3 - Article
AN - SCOPUS:44049115853
SN - 0020-1693
VL - 195
SP - 163
EP - 167
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -