Tungsten-organoimido chemistry. The crystal and molecular structures of [(n-C4H9)4N][W(NC6H4CH3)Cl5] and [(n-C4H9)4N][C7H7NH3][W2OCl8(NC6H4CH3)2]

Chen Qin, Deborah McClinton, Jon Zubieta

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The reaction of [(n-C4H9)4N]4[H3PW11O39] with [W(NC5H4CH3)Cl4]2 yields a mixture of [(n-C4H9)4N][W(NC6H4CH3)Cl5] (1) and [(n-C4H9)4N][C7H7NH3][W2OCl8(NC6H4CH3)2] (2). Crystal data: 1, monoclinic space group P21/c, a=10.950(2), b=11.254(3), c=12.920 Å, β=108.96(2)°, V=1506.0(6) Å3, Z=2, Dcalc=1.56 g cm-3, solution and refinement based on 2190 reflections converged at a conventional discrepancy value of 0.069; 2, monoclinic space group P21/c, a=14.001(8), b=26.68(1), c=15.278(9) Å, β=104.28(4)°, V=5534(3) Å3, Z=4, Dcalc=1.47 g cm-3, 4187 reflections, R=0.069.

Original languageEnglish (US)
Pages (from-to)163-167
Number of pages5
JournalInorganica Chimica Acta
Volume195
Issue number2
DOIs
StatePublished - May 15 1992

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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