Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms

Atieh Abu-Raqabah; Geoffrey Davies; Mohamed A. El-Sayed; Ahmed El-Toukhy; Shahid N. Shaikh; Jon Zubieta

doi:10.1016/S0020-1693(00)83796-2

Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms

Atieh Abu-Raqabah, Geoffrey Davies, Mohamed A. El-Sayed, Ahmed El-Toukhy, Shahid N. Shaikh, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

Tin complexes Sn(NS)₂Cl₂(D) and Sn(NS)₄(E) (NS is monoanionic S-methyl isopropylidenehydrazinecarbodithioate) are very good transmetalators of tetranuclear copper(I) target [NCuCl]₄ (I: N is N,N-diethylnicotinamide). An X-ray crystallographic study shows that D is cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV). Evidence that I reacts with 1 or 2 mol of D via strong precursors D·I and D₂·I that contain NS ligands bridging tin to copper is used to discuss the transmetalation sequence. The tin-containing transmetalation products include the remarkable air-stable copper(I)-tin(IV) complex N₃Cu₂Sn(NS)₂Cl₄ obtained from the reaction of I with equimolar E.

Original language	English (US)
Pages (from-to)	43-56
Number of pages	14
Journal	Inorganica Chimica Acta
Volume	193
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)83796-2
State	Published - Mar 2 1992

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Abu-Raqabah, A., Davies, G., El-Sayed, M. A., El-Toukhy, A., Shaikh, S. N., & Zubieta, J. (1992). Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms. Inorganica Chimica Acta, 193(1), 43-56. https://doi.org/10.1016/S0020-1693(00)83796-2

Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms. / Abu-Raqabah, Atieh; Davies, Geoffrey; El-Sayed, Mohamed A. et al.
In: Inorganica Chimica Acta, Vol. 193, No. 1, 02.03.1992, p. 43-56.

Research output: Contribution to journal › Article › peer-review

Abu-Raqabah, A, Davies, G, El-Sayed, MA, El-Toukhy, A, Shaikh, SN & Zubieta, J 1992, 'Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms', Inorganica Chimica Acta, vol. 193, no. 1, pp. 43-56. https://doi.org/10.1016/S0020-1693(00)83796-2

Abu-Raqabah A, Davies G, El-Sayed MA, El-Toukhy A, Shaikh SN, Zubieta J. Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms. Inorganica Chimica Acta. 1992 Mar 2;193(1):43-56. doi: 10.1016/S0020-1693(00)83796-2

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title = "Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms",

abstract = "Tin complexes Sn(NS)2Cl2(D) and Sn(NS)4(E) (NS is monoanionic S-methyl isopropylidenehydrazinecarbodithioate) are very good transmetalators of tetranuclear copper(I) target [NCuCl]4 (I: N is N,N-diethylnicotinamide). An X-ray crystallographic study shows that D is cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV). Evidence that I reacts with 1 or 2 mol of D via strong precursors D·I and D2·I that contain NS ligands bridging tin to copper is used to discuss the transmetalation sequence. The tin-containing transmetalation products include the remarkable air-stable copper(I)-tin(IV) complex N3Cu2Sn(NS)2Cl4 obtained from the reaction of I with equimolar E.",

author = "Atieh Abu-Raqabah and Geoffrey Davies and El-Sayed, {Mohamed A.} and Ahmed El-Toukhy and Shaikh, {Shahid N.} and Jon Zubieta",

note = "Funding Information: We gratefully acknowledget he National Science Foundation (Grants CHE-8717556a nd INT-8918985) for financial support of our work.",

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AU - Abu-Raqabah, Atieh

AU - Davies, Geoffrey

AU - El-Sayed, Mohamed A.

AU - El-Toukhy, Ahmed

AU - Shaikh, Shahid N.

AU - Zubieta, Jon

N1 - Funding Information: We gratefully acknowledget he National Science Foundation (Grants CHE-8717556a nd INT-8918985) for financial support of our work.

PY - 1992/3/2

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N2 - Tin complexes Sn(NS)2Cl2(D) and Sn(NS)4(E) (NS is monoanionic S-methyl isopropylidenehydrazinecarbodithioate) are very good transmetalators of tetranuclear copper(I) target [NCuCl]4 (I: N is N,N-diethylnicotinamide). An X-ray crystallographic study shows that D is cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV). Evidence that I reacts with 1 or 2 mol of D via strong precursors D·I and D2·I that contain NS ligands bridging tin to copper is used to discuss the transmetalation sequence. The tin-containing transmetalation products include the remarkable air-stable copper(I)-tin(IV) complex N3Cu2Sn(NS)2Cl4 obtained from the reaction of I with equimolar E.

AB - Tin complexes Sn(NS)2Cl2(D) and Sn(NS)4(E) (NS is monoanionic S-methyl isopropylidenehydrazinecarbodithioate) are very good transmetalators of tetranuclear copper(I) target [NCuCl]4 (I: N is N,N-diethylnicotinamide). An X-ray crystallographic study shows that D is cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV). Evidence that I reacts with 1 or 2 mol of D via strong precursors D·I and D2·I that contain NS ligands bridging tin to copper is used to discuss the transmetalation sequence. The tin-containing transmetalation products include the remarkable air-stable copper(I)-tin(IV) complex N3Cu2Sn(NS)2Cl4 obtained from the reaction of I with equimolar E.

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Transmetalation of tetranuclear copper complexes with tin transmetalators. Molecular structure of cis-dichloro-bis(trans-S-methyl isopropylidenehydrazinecarbodithioato)tin(IV) and consideration of transmetalation mechanisms

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