Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph 3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes

P. Fernández; J. Romero; J. A. García-Vázquez; A. Sousa-Pedrares; L. Valencia; J. Zubieta; P. Pérez-Lourido

doi:10.1016/j.jorganchem.2013.10.050

Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph ₃Sn{Ph₂PC₆H₄S-2}], [Sn{PhP(C ₆H₄S-2)₂}₂] and [Pb{Ph ₂P(O)C₆H₄S-2}₂]·1/2CH ₃OH·2H₂O complexes

P. Fernández, J. Romero, J. A. García-Vázquez, A. Sousa-Pedrares, L. Valencia, J. Zubieta, P. Pérez-Lourido

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The coordination capability of the phosphinothiol ligands Ph ₂PC₆H₄SH-2 and PhP(C₆H ₄SH-2)₂, towards two organotin (Ph₃SnCl, Ph₂SnCl₂) and the organolead Ph₂PbCl ₂ was studied. The complexes were characterized by microanalysis, FAB mass spectrometry, IR and NMR spectroscopy. Also, crystal structures of [Ph₃Sn{Ph₂PC₆H₄S-2}], [Sn{PhP(C ₆H₄S-2)₂}₂] and [Pb{Ph ₂P(O)C₆H₄S-2}₂]·1/2CH ₃OH·2H₂O complexes have been determined. The structure of [Ph₃Sn{Ph₂PC₆H₄S-2}] complex shows the triphenyltin fragment coordinated to one monoanionic phosphinothiol ligand acting as monodentate through the thiolate sulfur atom with the tin ion in a tetrahedral environment. The crystal structure of [Sn{PhP(C₆H₄S-2}₂] shows the metal ion in a distorted octahedral geometry. The geometry about the Pb in [Pb{Ph ₂P(O)C₆H₄S-2}₂]·1/2CH ₃OH·2H₂O complex is best described as distorted ψ-trigonal bipyramidal with the five position occupied by the active lone pair of metal. Intermolecular weak Pb-(η⁶-C₆H ₅) interactions between the lead electron pair and phenyl rings are also observed.

Original language	English (US)
Pages (from-to)	1-6
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	750
DOIs	https://doi.org/10.1016/j.jorganchem.2013.10.050
State	Published - 2014

Keywords

Lead complex
Organotin
Phosphinothiol ligands
X-ray crystal structure

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2013.10.050

Cite this

Fernández, P., Romero, J., García-Vázquez, J. A., Sousa-Pedrares, A., Valencia, L., Zubieta, J., & Pérez-Lourido, P. (2014). Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph ₃Sn{Ph₂PC₆H₄S-2}], [Sn{PhP(C ₆H₄S-2)₂}₂] and [Pb{Ph ₂P(O)C₆H₄S-2}₂]·1/2CH ₃OH·2H₂O complexes. Journal of Organometallic Chemistry, 750, 1-6. https://doi.org/10.1016/j.jorganchem.2013.10.050

Fernández, P, Romero, J, García-Vázquez, JA, Sousa-Pedrares, A, Valencia, L, Zubieta, J & Pérez-Lourido, P 2014, 'Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph ₃Sn{Ph₂PC₆H₄S-2}], [Sn{PhP(C ₆H₄S-2)₂}₂] and [Pb{Ph ₂P(O)C₆H₄S-2}₂]·1/2CH ₃OH·2H₂O complexes', Journal of Organometallic Chemistry, vol. 750, pp. 1-6. https://doi.org/10.1016/j.jorganchem.2013.10.050

@article{43f0cbd9fda4478b908dd37b58c1aa70,

title = "Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph 3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes",

abstract = "The coordination capability of the phosphinothiol ligands Ph 2PC6H4SH-2 and PhP(C6H 4SH-2)2, towards two organotin (Ph3SnCl, Ph2SnCl2) and the organolead Ph2PbCl 2 was studied. The complexes were characterized by microanalysis, FAB mass spectrometry, IR and NMR spectroscopy. Also, crystal structures of [Ph3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes have been determined. The structure of [Ph3Sn{Ph2PC6H4S-2}] complex shows the triphenyltin fragment coordinated to one monoanionic phosphinothiol ligand acting as monodentate through the thiolate sulfur atom with the tin ion in a tetrahedral environment. The crystal structure of [Sn{PhP(C6H4S-2}2] shows the metal ion in a distorted octahedral geometry. The geometry about the Pb in [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complex is best described as distorted ψ-trigonal bipyramidal with the five position occupied by the active lone pair of metal. Intermolecular weak Pb-(η6-C6H 5) interactions between the lead electron pair and phenyl rings are also observed.",

keywords = "Lead complex, Organotin, Phosphinothiol ligands, X-ray crystal structure",

author = "P. Fern{\'a}ndez and J. Romero and Garc{\'i}a-V{\'a}zquez, {J. A.} and A. Sousa-Pedrares and L. Valencia and J. Zubieta and P. P{\'e}rez-Lourido",

note = "Funding Information: We thank Ministerio Educaci{\'o}n Cultura y Deporte , Spain, BQU2002-01819 for financial support. ",

year = "2014",

doi = "10.1016/j.jorganchem.2013.10.050",

language = "English (US)",

volume = "750",

pages = "1--6",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Tin and lead phosphinothiolate derivatives. Crystal structures of [Ph 3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes

AU - Fernández, P.

AU - Romero, J.

AU - García-Vázquez, J. A.

AU - Sousa-Pedrares, A.

AU - Valencia, L.

AU - Zubieta, J.

AU - Pérez-Lourido, P.

N1 - Funding Information: We thank Ministerio Educación Cultura y Deporte , Spain, BQU2002-01819 for financial support.

PY - 2014

Y1 - 2014

N2 - The coordination capability of the phosphinothiol ligands Ph 2PC6H4SH-2 and PhP(C6H 4SH-2)2, towards two organotin (Ph3SnCl, Ph2SnCl2) and the organolead Ph2PbCl 2 was studied. The complexes were characterized by microanalysis, FAB mass spectrometry, IR and NMR spectroscopy. Also, crystal structures of [Ph3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes have been determined. The structure of [Ph3Sn{Ph2PC6H4S-2}] complex shows the triphenyltin fragment coordinated to one monoanionic phosphinothiol ligand acting as monodentate through the thiolate sulfur atom with the tin ion in a tetrahedral environment. The crystal structure of [Sn{PhP(C6H4S-2}2] shows the metal ion in a distorted octahedral geometry. The geometry about the Pb in [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complex is best described as distorted ψ-trigonal bipyramidal with the five position occupied by the active lone pair of metal. Intermolecular weak Pb-(η6-C6H 5) interactions between the lead electron pair and phenyl rings are also observed.

AB - The coordination capability of the phosphinothiol ligands Ph 2PC6H4SH-2 and PhP(C6H 4SH-2)2, towards two organotin (Ph3SnCl, Ph2SnCl2) and the organolead Ph2PbCl 2 was studied. The complexes were characterized by microanalysis, FAB mass spectrometry, IR and NMR spectroscopy. Also, crystal structures of [Ph3Sn{Ph2PC6H4S-2}], [Sn{PhP(C 6H4S-2)2}2] and [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complexes have been determined. The structure of [Ph3Sn{Ph2PC6H4S-2}] complex shows the triphenyltin fragment coordinated to one monoanionic phosphinothiol ligand acting as monodentate through the thiolate sulfur atom with the tin ion in a tetrahedral environment. The crystal structure of [Sn{PhP(C6H4S-2}2] shows the metal ion in a distorted octahedral geometry. The geometry about the Pb in [Pb{Ph 2P(O)C6H4S-2}2]·1/2CH 3OH·2H2O complex is best described as distorted ψ-trigonal bipyramidal with the five position occupied by the active lone pair of metal. Intermolecular weak Pb-(η6-C6H 5) interactions between the lead electron pair and phenyl rings are also observed.

KW - Lead complex

KW - Organotin

KW - Phosphinothiol ligands

KW - X-ray crystal structure

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U2 - 10.1016/j.jorganchem.2013.10.050

DO - 10.1016/j.jorganchem.2013.10.050

M3 - Article

AN - SCOPUS:84887968061

SN - 0022-328X

VL - 750

SP - 1

EP - 6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -