Abstract
The hydrothermal reactions of molybdenum(VI) oxide, 1,2-ethylene diphosphonic acid, 4-pyridyltetrazole (4-Hpt) and the appropriate metal acetate yielded a series of three-dimensional bimetallic oxides of the general formula [Mx(4-Hpt)y(H2O)z{Mo 5O15(O3PCH2CH2PO 3)}]·nhydrate (M = Co or Ni, x = 2, y = 2, z = 6; M = Cu, x = 4, y = 3, z = 1). The Co(II) and Ni(II) phases are isomorphous with structures constructed from the common {Mo5O15(O3PCH 2CH2PO3)}n 4n- chains linked through binuclear {M2(4-Hpt)2(H2O) 6}4+ subunits to provide the three-dimensional connectivity. The copper(I) species consists of the molybdophosphonate chains embedded in a framework of Cu(I) tetrahedra linked through the tetrazole nitrogen donors of the 4-Hpt ligands.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 89-94 |
| Number of pages | 6 |
| Journal | Inorganica Chimica Acta |
| Volume | 395 |
| DOIs | |
| State | Published - Jan 30 2013 |
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Keywords
- Hydrothermal synthesis
- Metal-pyridyltetrazole substructures
- Molybdophosphonate clusters and chains
- Polyoxometalate based metal-organic frameworks (POMOFs)
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Three-dimensional bimetallic oxides constructed from molybdophosphonate chains and secondary-metal/4-pyridyltetrazole components. / Jones, Stephanie; Darling, Kari; Zubieta, Jon A.
In: Inorganica Chimica Acta, Vol. 395, 30.01.2013, p. 89-94.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Three-dimensional bimetallic oxides constructed from molybdophosphonate chains and secondary-metal/4-pyridyltetrazole components
AU - Jones, Stephanie
AU - Darling, Kari
AU - Zubieta, Jon A
PY - 2013/1/30
Y1 - 2013/1/30
N2 - The hydrothermal reactions of molybdenum(VI) oxide, 1,2-ethylene diphosphonic acid, 4-pyridyltetrazole (4-Hpt) and the appropriate metal acetate yielded a series of three-dimensional bimetallic oxides of the general formula [Mx(4-Hpt)y(H2O)z{Mo 5O15(O3PCH2CH2PO 3)}]·nhydrate (M = Co or Ni, x = 2, y = 2, z = 6; M = Cu, x = 4, y = 3, z = 1). The Co(II) and Ni(II) phases are isomorphous with structures constructed from the common {Mo5O15(O3PCH 2CH2PO3)}n 4n- chains linked through binuclear {M2(4-Hpt)2(H2O) 6}4+ subunits to provide the three-dimensional connectivity. The copper(I) species consists of the molybdophosphonate chains embedded in a framework of Cu(I) tetrahedra linked through the tetrazole nitrogen donors of the 4-Hpt ligands.
AB - The hydrothermal reactions of molybdenum(VI) oxide, 1,2-ethylene diphosphonic acid, 4-pyridyltetrazole (4-Hpt) and the appropriate metal acetate yielded a series of three-dimensional bimetallic oxides of the general formula [Mx(4-Hpt)y(H2O)z{Mo 5O15(O3PCH2CH2PO 3)}]·nhydrate (M = Co or Ni, x = 2, y = 2, z = 6; M = Cu, x = 4, y = 3, z = 1). The Co(II) and Ni(II) phases are isomorphous with structures constructed from the common {Mo5O15(O3PCH 2CH2PO3)}n 4n- chains linked through binuclear {M2(4-Hpt)2(H2O) 6}4+ subunits to provide the three-dimensional connectivity. The copper(I) species consists of the molybdophosphonate chains embedded in a framework of Cu(I) tetrahedra linked through the tetrazole nitrogen donors of the 4-Hpt ligands.
KW - Hydrothermal synthesis
KW - Metal-pyridyltetrazole substructures
KW - Molybdophosphonate clusters and chains
KW - Polyoxometalate based metal-organic frameworks (POMOFs)
UR - http://www.scopus.com/inward/record.url?scp=84870894402&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84870894402&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2012.10.022
DO - 10.1016/j.ica.2012.10.022
M3 - Article
AN - SCOPUS:84870894402
VL - 395
SP - 89
EP - 94
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -