TY - JOUR
T1 - The synthesis and structural characterization of [ReCl2(PPh 3)2(NNHCOPh)(NHNHCO-Ph)]·1/2Et2O, a complex exhibiting linear hydrazido(2-) ligation and end-on hydrazido(1-) ligation
AU - Nicholson, Terrence
AU - Zubieta, Jon
PY - 1985/1/1
Y1 - 1985/1/1
N2 - The title compound was prepared by treating [ReCl2(PPh 3)2(NNCOPh)] with excess of benzoylhydrazine in methanol solution: X-ray crystallography reveals a unique example of monohapto-co- ordination by a hydrazido(1-) grouping, -NHNHR, and an unusual instance of mixed hydrazido(2-) and hydrazido(1-) co-ordination to a metal site.
AB - The title compound was prepared by treating [ReCl2(PPh 3)2(NNCOPh)] with excess of benzoylhydrazine in methanol solution: X-ray crystallography reveals a unique example of monohapto-co- ordination by a hydrazido(1-) grouping, -NHNHR, and an unusual instance of mixed hydrazido(2-) and hydrazido(1-) co-ordination to a metal site.
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U2 - 10.1039/C39850000367
DO - 10.1039/C39850000367
M3 - Article
AN - SCOPUS:37049106772
SN - 0022-4936
SP - 367
EP - 368
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 6
ER -