The synthesis and structural characterization of [ReCl2(PPh 3)2(NNHCOPh)(NHNHCO-Ph)]·1/2Et2O, a complex exhibiting linear hydrazido(2-) ligation and end-on hydrazido(1-) ligation

Terrence Nicholson; Jon Zubieta

doi:10.1039/C39850000367

The synthesis and structural characterization of [ReCl₂(PPh ₃)₂(NNHCOPh)(NHNHCO-Ph)]·1/2Et₂O, a complex exhibiting linear hydrazido(2-) ligation and end-on hydrazido(1-) ligation

Terrence Nicholson, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The title compound was prepared by treating [ReCl₂(PPh ₃)₂(NNCOPh)] with excess of benzoylhydrazine in methanol solution: X-ray crystallography reveals a unique example of monohapto-co- ordination by a hydrazido(1-) grouping, -NHNHR, and an unusual instance of mixed hydrazido(2-) and hydrazido(1-) co-ordination to a metal site.

Original language	English (US)
Pages (from-to)	367-368
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
DOIs	https://doi.org/10.1039/C39850000367
State	Published - Jan 1 1985
Externally published	Yes

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Molecular Medicine

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The synthesis and structural characterization of [ReCl₂(PPh ₃)₂(NNHCOPh)(NHNHCO-Ph)]·1/2Et₂O, a complex exhibiting linear hydrazido(2-) ligation and end-on hydrazido(1-) ligation. / Nicholson, Terrence; Zubieta, Jon.

In: Journal of the Chemical Society, Chemical Communications, No. 6, 01.01.1985, p. 367-368.

Research output: Contribution to journal › Article › peer-review

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abstract = "The title compound was prepared by treating [ReCl2(PPh 3)2(NNCOPh)] with excess of benzoylhydrazine in methanol solution: X-ray crystallography reveals a unique example of monohapto-co- ordination by a hydrazido(1-) grouping, -NHNHR, and an unusual instance of mixed hydrazido(2-) and hydrazido(1-) co-ordination to a metal site.",

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AB - The title compound was prepared by treating [ReCl2(PPh 3)2(NNCOPh)] with excess of benzoylhydrazine in methanol solution: X-ray crystallography reveals a unique example of monohapto-co- ordination by a hydrazido(1-) grouping, -NHNHR, and an unusual instance of mixed hydrazido(2-) and hydrazido(1-) co-ordination to a metal site.

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The synthesis and structural characterization of [ReCl₂(PPh ₃)₂(NNHCOPh)(NHNHCO-Ph)]·1/2Et₂O, a complex exhibiting linear hydrazido(2-) ligation and end-on hydrazido(1-) ligation

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