TY - JOUR
T1 - The synthesis and crystal and molecular structure of mer-tris(3-trimethylsilyl-2-pyridinethiolato)cobalt(III)
AU - Block, Eric
AU - Kang, Hyunkyu
AU - Ofori-Okai, Gabriel
AU - Zubieta, Jon
PY - 1991/10/1
Y1 - 1991/10/1
N2 - The room temperature reaction of [Co(H2O)6]Cl2 with 3-trimethylsilyl-2-pyridinethiol in methanol yields [Co(2-SC5H3N-3-SiMe3)3]. The crystal structure determination revealed the meridional ligand arrangement, as previously reported for the analogous [Co(2-SC5H4N]. Crystal data: C24H36N3Si3S3Co, monoclinic space group P21/c, a = 9.416(2), b = 29.163(4), c = 12.371(2) Å. β = 106.81(1)°, Z = 4, Dcalc = 1.23 g cm-3; structure solution and refinement based on 1032 reflections with Fo≥6o(Fo) (Mo Kα, λ = 0.71073 Å) converged at R = 0.069.
AB - The room temperature reaction of [Co(H2O)6]Cl2 with 3-trimethylsilyl-2-pyridinethiol in methanol yields [Co(2-SC5H3N-3-SiMe3)3]. The crystal structure determination revealed the meridional ligand arrangement, as previously reported for the analogous [Co(2-SC5H4N]. Crystal data: C24H36N3Si3S3Co, monoclinic space group P21/c, a = 9.416(2), b = 29.163(4), c = 12.371(2) Å. β = 106.81(1)°, Z = 4, Dcalc = 1.23 g cm-3; structure solution and refinement based on 1032 reflections with Fo≥6o(Fo) (Mo Kα, λ = 0.71073 Å) converged at R = 0.069.
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U2 - 10.1016/S0020-1693(00)80918-4
DO - 10.1016/S0020-1693(00)80918-4
M3 - Article
AN - SCOPUS:0002224127
SN - 0020-1693
VL - 188
SP - 61
EP - 66
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -