The synthesis and characterization of two new copper phosphonates: The one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O and the molecular [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)

R. C. Finn; J. Zubieta

doi:10.1016/S0020-1693(02)00702-8

The synthesis and characterization of two new copper phosphonates: The one-dimensional [Cu(terpy)(HO₃PCH₂CH₂PO₃H)] ·4H₂O and the molecular [{Cu(phen)(H₂O)}₂(O₃PCH₂CH ₂PO₃)]·9H₂O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)

R. C. Finn, J. Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

The reaction of copper with 1,2-ethylene diphosphonic acid and 2,2′:6′,2″-terpyridine and o-phenanthroline under hydrothermal conditions resulted in the one-dimensional [Cu(terpy)(HO₃PCH₂CH₂PO₃H)] ·4H₂O (1·4H₂O) and the molecular species [{Cu(phen)(H₂O)}₂(O₃PCH₂CH ₂PO₃)]·9H₂O (2·9H₂O), which were isolated by slow evaporation. Crystal data: (1·4H₂O) C₁₇H₂₁CuN₃O₈P₂, triclinic, P1̄; a=10.6468(6) Å, b=14.2195(7) Å, c=14.2906(7) Å, α=73.466(1)°, β=89.020(1)°, γ=71.597(1)°, V=1961.7(2) Å³, Z=4; (2·9H₂O) C₂₆H₄₂Cu₂N₄O₁₇P ₂, orthorhombic, Pna2₁; a=14.4018(6) Å, b=11.9020(5) Å, c=20.6049(8) Å, V=3531.9(2) Å³, Z=4.

Original language	English (US)
Pages (from-to)	191-194
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	332
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(02)00702-8
State	Published - Apr 17 2002

Keywords

Copper phosphonates
Crystal structures
Hydrothermal synthesis
One-dimensional materials

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(02)00702-8

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The synthesis and characterization of two new copper phosphonates: The one-dimensional [Cu(terpy)(HO₃PCH₂CH₂PO₃H)] ·4H₂O and the molecular [{Cu(phen)(H₂O)}₂(O₃PCH₂CH ₂PO₃)]·9H₂O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline). / Finn, R. C.; Zubieta, J.
In: Inorganica Chimica Acta, Vol. 332, No. 1, 17.04.2002, p. 191-194.

Research output: Contribution to journal › Article › peer-review

Finn, RC & Zubieta, J 2002, 'The synthesis and characterization of two new copper phosphonates: The one-dimensional [Cu(terpy)(HO₃PCH₂CH₂PO₃H)] ·4H₂O and the molecular [{Cu(phen)(H₂O)}₂(O₃PCH₂CH ₂PO₃)]·9H₂O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)', Inorganica Chimica Acta, vol. 332, no. 1, pp. 191-194. https://doi.org/10.1016/S0020-1693(02)00702-8

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title = "The synthesis and characterization of two new copper phosphonates: The one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O and the molecular [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)",

abstract = "The reaction of copper with 1,2-ethylene diphosphonic acid and 2,2′:6′,2″-terpyridine and o-phenanthroline under hydrothermal conditions resulted in the one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O (1·4H2O) and the molecular species [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (2·9H2O), which were isolated by slow evaporation. Crystal data: (1·4H2O) C17H21CuN3O8P2, triclinic, P{\=1}; a=10.6468(6) {\AA}, b=14.2195(7) {\AA}, c=14.2906(7) {\AA}, α=73.466(1)°, β=89.020(1)°, γ=71.597(1)°, V=1961.7(2) {\AA}3, Z=4; (2·9H2O) C26H42Cu2N4O17P 2, orthorhombic, Pna21; a=14.4018(6) {\AA}, b=11.9020(5) {\AA}, c=20.6049(8) {\AA}, V=3531.9(2) {\AA}3, Z=4.",

keywords = "Copper phosphonates, Crystal structures, Hydrothermal synthesis, One-dimensional materials",

author = "Finn, {R. C.} and J. Zubieta",

year = "2002",

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doi = "10.1016/S0020-1693(02)00702-8",

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T1 - The synthesis and characterization of two new copper phosphonates

T2 - The one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O and the molecular [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (terpy=2,2′:6′,2″-terpyridine, phen=1,10-phenanthroline)

AU - Finn, R. C.

AU - Zubieta, J.

PY - 2002/4/17

Y1 - 2002/4/17

N2 - The reaction of copper with 1,2-ethylene diphosphonic acid and 2,2′:6′,2″-terpyridine and o-phenanthroline under hydrothermal conditions resulted in the one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O (1·4H2O) and the molecular species [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (2·9H2O), which were isolated by slow evaporation. Crystal data: (1·4H2O) C17H21CuN3O8P2, triclinic, P1̄; a=10.6468(6) Å, b=14.2195(7) Å, c=14.2906(7) Å, α=73.466(1)°, β=89.020(1)°, γ=71.597(1)°, V=1961.7(2) Å3, Z=4; (2·9H2O) C26H42Cu2N4O17P 2, orthorhombic, Pna21; a=14.4018(6) Å, b=11.9020(5) Å, c=20.6049(8) Å, V=3531.9(2) Å3, Z=4.

AB - The reaction of copper with 1,2-ethylene diphosphonic acid and 2,2′:6′,2″-terpyridine and o-phenanthroline under hydrothermal conditions resulted in the one-dimensional [Cu(terpy)(HO3PCH2CH2PO3H)] ·4H2O (1·4H2O) and the molecular species [{Cu(phen)(H2O)}2(O3PCH2CH 2PO3)]·9H2O (2·9H2O), which were isolated by slow evaporation. Crystal data: (1·4H2O) C17H21CuN3O8P2, triclinic, P1̄; a=10.6468(6) Å, b=14.2195(7) Å, c=14.2906(7) Å, α=73.466(1)°, β=89.020(1)°, γ=71.597(1)°, V=1961.7(2) Å3, Z=4; (2·9H2O) C26H42Cu2N4O17P 2, orthorhombic, Pna21; a=14.4018(6) Å, b=11.9020(5) Å, c=20.6049(8) Å, V=3531.9(2) Å3, Z=4.

KW - Copper phosphonates

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KW - Hydrothermal synthesis

KW - One-dimensional materials

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