The solvatothermal synthesis and the crystal structure of polymeric N-methylpyridinium octamolybdate(VI), (Me-NC5H5)4n[Mo8 O26]n

Barbara Modec; Jurij V. Brenčič; Jon Zubieta

doi:10.1016/S1387-7003(03)00029-7

The solvatothermal synthesis and the crystal structure of polymeric N-methylpyridinium octamolybdate(VI), (Me-NC₅H₅)_4n[Mo₈ O₂₆]_n

Barbara Modec, Jurij V. Brenčič, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The reaction of (PyH)₂[MoOCl₅] with pyridine and methanol in the presence of CoCl₂·6H₂O and H₂C₂O₄·2H₂O at 130 °C under solvatothermal conditions afforded (Me-NC₅H₅)_4n[Mo₈ O₂₆]_n 1. The structure consists of infinite molybdenum oxide chains bearing a negative charge and N-methylpyridinium cations. Eight {MoO₆} octahedra are arranged in an edge-sharing manner to form compact octamolybdate subunits which are connected through pairs of Mo-O-Mo bridges into extended one-dimensional arrays.

Original language	English (US)
Pages (from-to)	506-512
Number of pages	7
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	5
DOIs	https://doi.org/10.1016/S1387-7003(03)00029-7
State	Published - May 1 2003

Keywords

Crystal structure
Octamolybdate
Polymeric structures
Polyoxometalates
Solvatothermal synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S1387-7003(03)00029-7

Cite this

@article{b93c4002ab4f4ca88cac6dc84fdbd27c,

title = "The solvatothermal synthesis and the crystal structure of polymeric N-methylpyridinium octamolybdate(VI), (Me-NC5H5)4n[Mo8 O26]n",

abstract = "The reaction of (PyH)2[MoOCl5] with pyridine and methanol in the presence of CoCl2·6H2O and H2C2O4·2H2O at 130 °C under solvatothermal conditions afforded (Me-NC5H5)4n[Mo8 O26]n 1. The structure consists of infinite molybdenum oxide chains bearing a negative charge and N-methylpyridinium cations. Eight {MoO6} octahedra are arranged in an edge-sharing manner to form compact octamolybdate subunits which are connected through pairs of Mo-O-Mo bridges into extended one-dimensional arrays.",

keywords = "Crystal structure, Octamolybdate, Polymeric structures, Polyoxometalates, Solvatothermal synthesis",

author = "Barbara Modec and Bren{\v c}i{\v c}, {Jurij V.} and Jon Zubieta",

note = "Funding Information: We are grateful to the Slovenian Ministry of Education, Science and Sport for supporting this work through research Grants PS-0508-0103 and SLO-US-2001/15. The work at Syracuse University was supported by a grant from the National Science Foundation, CHE9987471.",

year = "2003",

month = may,

day = "1",

doi = "10.1016/S1387-7003(03)00029-7",

language = "English (US)",

volume = "6",

pages = "506--512",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "5",

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TY - JOUR

T1 - The solvatothermal synthesis and the crystal structure of polymeric N-methylpyridinium octamolybdate(VI), (Me-NC5H5)4n[Mo8 O26]n

AU - Modec, Barbara

AU - Brenčič, Jurij V.

AU - Zubieta, Jon

N1 - Funding Information: We are grateful to the Slovenian Ministry of Education, Science and Sport for supporting this work through research Grants PS-0508-0103 and SLO-US-2001/15. The work at Syracuse University was supported by a grant from the National Science Foundation, CHE9987471.

PY - 2003/5/1

Y1 - 2003/5/1

N2 - The reaction of (PyH)2[MoOCl5] with pyridine and methanol in the presence of CoCl2·6H2O and H2C2O4·2H2O at 130 °C under solvatothermal conditions afforded (Me-NC5H5)4n[Mo8 O26]n 1. The structure consists of infinite molybdenum oxide chains bearing a negative charge and N-methylpyridinium cations. Eight {MoO6} octahedra are arranged in an edge-sharing manner to form compact octamolybdate subunits which are connected through pairs of Mo-O-Mo bridges into extended one-dimensional arrays.

AB - The reaction of (PyH)2[MoOCl5] with pyridine and methanol in the presence of CoCl2·6H2O and H2C2O4·2H2O at 130 °C under solvatothermal conditions afforded (Me-NC5H5)4n[Mo8 O26]n 1. The structure consists of infinite molybdenum oxide chains bearing a negative charge and N-methylpyridinium cations. Eight {MoO6} octahedra are arranged in an edge-sharing manner to form compact octamolybdate subunits which are connected through pairs of Mo-O-Mo bridges into extended one-dimensional arrays.

KW - Crystal structure

KW - Octamolybdate

KW - Polymeric structures

KW - Polyoxometalates

KW - Solvatothermal synthesis

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U2 - 10.1016/S1387-7003(03)00029-7

DO - 10.1016/S1387-7003(03)00029-7

M3 - Article

AN - SCOPUS:0037401838

SN - 1387-7003

VL - 6

SP - 506

EP - 512

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -