The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3]

R. Castro; J. Romero; J. A. Garcia-Vazquez; A. Sousa; Y. D. Chang; J. Zubieta

doi:10.1016/0020-1693(95)04790-5

The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]

R. Castro, J. Romero, J. A. Garcia-Vazquez, A. Sousa, Y. D. Chang, J. Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

μ-[1,2-Bis(diphenylphosphino)ethane]bis(3-trimethylsilyl;-pyridine-2- thiolate-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃], was obtained by reaction of [Cu(3-Me₃Sipyt)] with 1,2-bis(diphenylphosphino)ethane (dppe) in acetone. The compound is dimeric with dppe molecules acting as both bridging and chelating ligands and the thione coordinating in the monoanionic form through the sulfur atom. The environment around the copper is distorted tetrahedral. Crystal data: P2₁/n, a=16.640(3), b=14.437(3), c=18.321(4) Å, β=101.41(3)°, V=4312(1) Å³, Z=2, D_calc=1.299 g cm^-3, R=0.0627 for 2723 reflections.

Original language	English (US)
Pages (from-to)	119-122
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	245
Issue number	1
DOIs	https://doi.org/10.1016/0020-1693(95)04790-5
State	Published - Apr 1 1996

Keywords

Copper complexes
Crystal structures
Dinuclear complexes
Diphosphine complexes
Thiolate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Castro, R., Romero, J., Garcia-Vazquez, J. A., Sousa, A., Chang, Y. D., & Zubieta, J. (1996). The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]. Inorganica Chimica Acta, 245(1), 119-122. https://doi.org/10.1016/0020-1693(95)04790-5

The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]. / Castro, R.; Romero, J.; Garcia-Vazquez, J. A. et al.
In: Inorganica Chimica Acta, Vol. 245, No. 1, 01.04.1996, p. 119-122.

Research output: Contribution to journal › Article › peer-review

Castro, R, Romero, J, Garcia-Vazquez, JA, Sousa, A, Chang, YD & Zubieta, J 1996, 'The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]', Inorganica Chimica Acta, vol. 245, no. 1, pp. 119-122. https://doi.org/10.1016/0020-1693(95)04790-5

Castro R, Romero J, Garcia-Vazquez JA, Sousa A, Chang YD, Zubieta J. The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]. Inorganica Chimica Acta. 1996 Apr 1;245(1):119-122. doi: 10.1016/0020-1693(95)04790-5

Castro, R. ; Romero, J. ; Garcia-Vazquez, J. A. et al. / The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu₂(3-Me₃Sipyt)₂(dppe)₃]. In: Inorganica Chimica Acta. 1996 ; Vol. 245, No. 1. pp. 119-122.

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title = "The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3]",

abstract = "μ-[1,2-Bis(diphenylphosphino)ethane]bis(3-trimethylsilyl;-pyridine-2- thiolate-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3], was obtained by reaction of [Cu(3-Me3Sipyt)] with 1,2-bis(diphenylphosphino)ethane (dppe) in acetone. The compound is dimeric with dppe molecules acting as both bridging and chelating ligands and the thione coordinating in the monoanionic form through the sulfur atom. The environment around the copper is distorted tetrahedral. Crystal data: P21/n, a=16.640(3), b=14.437(3), c=18.321(4) {\AA}, β=101.41(3)°, V=4312(1) {\AA}3, Z=2, Dcalc=1.299 g cm-3, R=0.0627 for 2723 reflections.",

keywords = "Copper complexes, Crystal structures, Dinuclear complexes, Diphosphine complexes, Thiolate complexes",

author = "R. Castro and J. Romero and Garcia-Vazquez, {J. A.} and A. Sousa and Chang, {Y. D.} and J. Zubieta",

note = "Funding Information: We thank the Xunta de Galicia (XUGA20309B93)) Spain, for financial support, and the Petroleum Research Fund,",

year = "1996",

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doi = "10.1016/0020-1693(95)04790-5",

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T1 - The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3]

AU - Castro, R.

AU - Romero, J.

AU - Garcia-Vazquez, J. A.

AU - Sousa, A.

AU - Chang, Y. D.

AU - Zubieta, J.

N1 - Funding Information: We thank the Xunta de Galicia (XUGA20309B93)) Spain, for financial support, and the Petroleum Research Fund,

PY - 1996/4/1

Y1 - 1996/4/1

N2 - μ-[1,2-Bis(diphenylphosphino)ethane]bis(3-trimethylsilyl;-pyridine-2- thiolate-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3], was obtained by reaction of [Cu(3-Me3Sipyt)] with 1,2-bis(diphenylphosphino)ethane (dppe) in acetone. The compound is dimeric with dppe molecules acting as both bridging and chelating ligands and the thione coordinating in the monoanionic form through the sulfur atom. The environment around the copper is distorted tetrahedral. Crystal data: P21/n, a=16.640(3), b=14.437(3), c=18.321(4) Å, β=101.41(3)°, V=4312(1) Å3, Z=2, Dcalc=1.299 g cm-3, R=0.0627 for 2723 reflections.

AB - μ-[1,2-Bis(diphenylphosphino)ethane]bis(3-trimethylsilyl;-pyridine-2- thiolate-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3], was obtained by reaction of [Cu(3-Me3Sipyt)] with 1,2-bis(diphenylphosphino)ethane (dppe) in acetone. The compound is dimeric with dppe molecules acting as both bridging and chelating ligands and the thione coordinating in the monoanionic form through the sulfur atom. The environment around the copper is distorted tetrahedral. Crystal data: P21/n, a=16.640(3), b=14.437(3), c=18.321(4) Å, β=101.41(3)°, V=4312(1) Å3, Z=2, Dcalc=1.299 g cm-3, R=0.0627 for 2723 reflections.

KW - Copper complexes

KW - Crystal structures

KW - Dinuclear complexes

KW - Diphosphine complexes

KW - Thiolate complexes

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