The reaction of copper 3-trimethylsilylpyridine-2-thiolate with bis(diphenylphosphino)ethane. Crystal structure of μ-[1,2-bis (diphenylphosphino)ethane]bis(3-trimethylsilylpyridine-2-thiolato-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3]

R. Castro, J. Romero, J. A. Garcia-Vazquez, A. Sousa, Y. D. Chang, Jon A Zubieta

Research output: Contribution to journalArticle

31 Scopus citations

Abstract

μ-[1,2-Bis(diphenylphosphino)ethane]bis(3-trimethylsilyl;-pyridine-2- thiolate-S) [1,2-bis(diphenylphosphino)ethane]dicopper(I), [Cu2(3-Me3Sipyt)2(dppe)3], was obtained by reaction of [Cu(3-Me3Sipyt)] with 1,2-bis(diphenylphosphino)ethane (dppe) in acetone. The compound is dimeric with dppe molecules acting as both bridging and chelating ligands and the thione coordinating in the monoanionic form through the sulfur atom. The environment around the copper is distorted tetrahedral. Crystal data: P21/n, a=16.640(3), b=14.437(3), c=18.321(4) Å, β=101.41(3)°, V=4312(1) Å3, Z=2, Dcalc=1.299 g cm-3, R=0.0627 for 2723 reflections.

Original languageEnglish (US)
Pages (from-to)119-122
Number of pages4
JournalInorganica Chimica Acta
Volume245
Issue number1
DOIs
StatePublished - Apr 1 1996

    Fingerprint

Keywords

  • Copper complexes
  • Crystal structures
  • Dinuclear complexes
  • Diphosphine complexes
  • Thiolate complexes

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this