The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)6(tBuPO3)8Cl], [(VO)4{PhP(O)2OP(O)2Ph}4Cl], and [V18O25(H2O)2(PHPO3)20Cl4]4− with Encapsulated Chloride Anions Prepared from Simple Precursors

José Salta, Qin Chen, Yuan‐Da ‐D Chang, Jon Zubieta

Research output: Contribution to journalArticle

106 Scopus citations

Abstract

Simply heating a suspension of [Ph4P][VO2Cl2] and tBuPO3H2 in acetonitrile in a sealed tube to 100°C gave the first of the three title compounds as dark green crystals. The structure of this compound (shown on the right) could not have a more pleasing simplicity. Relatively minor changes in the starting materials led to other, more complicated products. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)757-760
Number of pages4
JournalAngewandte Chemie International Edition in English
Volume33
Issue number7
DOIs
StatePublished - Apr 18 1994

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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