The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)6(tBuPO3)8Cl], [(VO)4{PhP(O)2OP(O)2Ph}4Cl]−, and [V18O25(H2O)2(PHPO3)20Cl4]4− with Encapsulated Chloride Anions Prepared from Simple Precursors

José Salta; Qin Chen; Yuan‐Da ‐D Chang; Jon Zubieta

doi:10.1002/anie.199407571

The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors

José Salta, Qin Chen, Yuan‐Da ‐D Chang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Abstract

Simply heating a suspension of [Ph₄P][VO₂Cl₂] and tBuPO₃H₂ in acetonitrile in a sealed tube to 100°C gave the first of the three title compounds as dark green crystals. The structure of this compound (shown on the right) could not have a more pleasing simplicity. Relatively minor changes in the starting materials led to other, more complicated products. (Figure Presented.)

Original language	English (US)
Pages (from-to)	757-760
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	7
DOIs	https://doi.org/10.1002/anie.199407571
State	Published - Apr 18 1994

ASJC Scopus subject areas

Catalysis
General Chemistry

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Salta, J., Chen, Q., Chang, YD. D., & Zubieta, J. (1994). The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors. Angewandte Chemie International Edition in English, 33(7), 757-760. https://doi.org/10.1002/anie.199407571

The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors. / Salta, José; Chen, Qin; Chang, Yuan‐Da ‐D et al.
In: Angewandte Chemie International Edition in English, Vol. 33, No. 7, 18.04.1994, p. 757-760.

Research output: Contribution to journal › Article › peer-review

Salta, J, Chen, Q, Chang, YDD & Zubieta, J 1994, 'The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors', Angewandte Chemie International Edition in English, vol. 33, no. 7, pp. 757-760. https://doi.org/10.1002/anie.199407571

Salta J, Chen Q, Chang YDD, Zubieta J. The Oxovanadium–Organophosphonate System: Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors. Angewandte Chemie International Edition in English. 1994 Apr 18;33(7):757-760. doi: 10.1002/anie.199407571

Salta, José ; Chen, Qin ; Chang, Yuan‐Da ‐D et al. / The Oxovanadium–Organophosphonate System : Complex Cluster Structures [(VO)₆(tBuPO₃)₈Cl], [(VO)₄{PhP(O)₂OP(O)₂Ph}₄Cl]⁻, and [V₁₈O₂₅(H₂O)₂(PHPO₃)₂₀Cl₄]⁴⁻ with Encapsulated Chloride Anions Prepared from Simple Precursors. In: Angewandte Chemie International Edition in English. 1994 ; Vol. 33, No. 7. pp. 757-760.

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