The Oxovanadium–Organoarsonate System: [2CH3OH ⊂ V12O14(OH)4(PhAsO3)10]4− and [2H2O ⊂ V12O12(OH)2(H2O)2(PhAsO3)10− (PhAsO3H)4]2−, Clusters with Nanometer Dimensions and Cavities for Neutral Molecules

M. Ishaque Khan, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

74 Scopus citations


Neutral molecules are encapsulated in the cluster anions in the title, which were produced by solvothermal reactions of [nBu4N]3[H3V10O28] and PhAsO3H2 in CH3OH/H2O (99:1) with and without Et4NCl. The structures are shown schematically below. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)760-762
Number of pages3
JournalAngewandte Chemie International Edition in English
Issue number7
StatePublished - Apr 18 1994

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)


Dive into the research topics of 'The Oxovanadium–Organoarsonate System: [2CH<sub>3</sub>OH ⊂ V<sub>12</sub>O<sub>14</sub>(OH)<sub>4</sub>(PhAsO<sub>3</sub>)<sub>10</sub>]<sup>4−</sup> and [2H<sub>2</sub>O ⊂ V<sub>12</sub>O<sub>12</sub>(OH)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>(PhAsO<sub>3</sub>)<sub>10−</sub> (PhAsO<sub>3</sub>H)<sub>4</sub>]<sup>2−</sup>, Clusters with Nanometer Dimensions and Cavities for Neutral Molecules'. Together they form a unique fingerprint.

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