The Oxovanadium–Organoarsonate System: [2CH3OH ⊂ V12O14(OH)4(PhAsO3)10]4− and [2H2O ⊂ V12O12(OH)2(H2O)2(PhAsO3)10− (PhAsO3H)4]2−, Clusters with Nanometer Dimensions and Cavities for Neutral Molecules

M. Ishaque Khan, Jon Zubieta

Research output: Contribution to journalArticle

72 Scopus citations

Abstract

Neutral molecules are encapsulated in the cluster anions in the title, which were produced by solvothermal reactions of [nBu4N]3[H3V10O28] and PhAsO3H2 in CH3OH/H2O (99:1) with and without Et4NCl. The structures are shown schematically below. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)760-762
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume33
Issue number7
DOIs
StatePublished - Apr 18 1994

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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