The metal influence on the structural chemistry of alkynes: Synthetic, spectroscopic and structural studies on magnesium acetylides

Marites A. Guino-O; Eva Baker; Karin Ruhlandt-Senge

doi:10.1080/00958970701732790

The metal influence on the structural chemistry of alkynes: Synthetic, spectroscopic and structural studies on magnesium acetylides

Marites A. Guino-O, Eva Baker, Karin Ruhlandt-Senge

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

A family of magnesium acetylides was prepared by treating Bu2Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs.

Original language	English (US)
Pages (from-to)	125-136
Number of pages	12
Journal	Journal of Coordination Chemistry
Volume	61
Issue number	1
DOIs	https://doi.org/10.1080/00958970701732790
State	Published - 2008

Keywords

Alkane elimination
Alkynes
Donor effects
Magnesium
Structure elucidation

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958970701732790

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title = "The metal influence on the structural chemistry of alkynes: Synthetic, spectroscopic and structural studies on magnesium acetylides",

abstract = "A family of magnesium acetylides was prepared by treating Bu2Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs.",

keywords = "Alkane elimination, Alkynes, Donor effects, Magnesium, Structure elucidation",

author = "Guino-O, {Marites A.} and Eva Baker and Karin Ruhlandt-Senge",

note = "Funding Information: We gratefully acknowledge support from the National Science Foundation (CHE-0505863). Purchase of the X-ray diffraction equipment was made possible with grants from the National Science Foundation (CHE-9527858), Syracuse University and the WM Keck Foundation. E. B thanks the Department of Homeland Security for a scholarship.",

year = "2008",

doi = "10.1080/00958970701732790",

language = "English (US)",

volume = "61",

pages = "125--136",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - The metal influence on the structural chemistry of alkynes

T2 - Synthetic, spectroscopic and structural studies on magnesium acetylides

AU - Guino-O, Marites A.

AU - Baker, Eva

AU - Ruhlandt-Senge, Karin

N1 - Funding Information: We gratefully acknowledge support from the National Science Foundation (CHE-0505863). Purchase of the X-ray diffraction equipment was made possible with grants from the National Science Foundation (CHE-9527858), Syracuse University and the WM Keck Foundation. E. B thanks the Department of Homeland Security for a scholarship.

PY - 2008

Y1 - 2008

N2 - A family of magnesium acetylides was prepared by treating Bu2Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs.

AB - A family of magnesium acetylides was prepared by treating Bu2Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs.

KW - Alkane elimination

KW - Alkynes

KW - Donor effects

KW - Magnesium

KW - Structure elucidation

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JF - Journal of Coordination Chemistry

IS - 1

ER -

The metal influence on the structural chemistry of alkynes: Synthetic, spectroscopic and structural studies on magnesium acetylides

Abstract

Keywords

ASJC Scopus subject areas

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