The metal influence on the structural chemistry of alkynes

Synthetic, spectroscopic and structural studies on magnesium acetylides

Marites A. Guino-O, Eva Baker, Karin Ruhlandt

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A family of magnesium acetylides was prepared by treating Bu2Mg with two equivalents of various alkyne ligands in the presence of different donors. The resulting complexes were examined for the influence of ligand and donors on the spectroscopic and structural properties of the target compounds. The magnesium complexes are compared to the heavier alkaline earth metal analogs.

Original languageEnglish (US)
Pages (from-to)125-136
Number of pages12
JournalJournal of Coordination Chemistry
Volume61
Issue number1
DOIs
StatePublished - 2008

Fingerprint

Alkynes
alkynes
Magnesium
magnesium
Metals
Alkaline Earth Metals
Ligands
chemistry
Alkaline earth metals
ligands
alkaline earth metals
heavy metals
metals
Heavy metals
Structural properties
analogs

Keywords

  • Alkane elimination
  • Alkynes
  • Donor effects
  • Magnesium
  • Structure elucidation

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

The metal influence on the structural chemistry of alkynes : Synthetic, spectroscopic and structural studies on magnesium acetylides. / Guino-O, Marites A.; Baker, Eva; Ruhlandt, Karin.

In: Journal of Coordination Chemistry, Vol. 61, No. 1, 2008, p. 125-136.

Research output: Contribution to journalArticle

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