The hydrothermal syntheses and characterization of one-and two-dimensional structures constructed from metal–organic derivatives of polyoxometalates: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo5O15){O3P(CH2)4PO3}]H2O and [{Cu2(tpypyz)(H2O)2}(Mo5O15)(O3PCH2CH2PO3)]5.5H2O [bpy = 2,2’-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]

Robert C. Finn, Eric Burkholder, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

116 Scopus citations

Abstract

The hydrothermal reaction of CuSO4·5H2O, Na2MoO4·2H2O and 2,2’-bipyridine with the bridging diphosphonate ligand H2O3P(CH2)4PO3H 2 yields the one-dimensional chain [{Cu(bpy)2}{Cu(bpy)(H2O)2 }(Mo5O15){O3P(CH2) 4PO3}]·H2O; the introduction of a second bridging component in the reaction of Cu(MeCO2)2·H2O, MoO3, H2O3PCH2CH2PO3H 2and tetra(2-pyridyl)pyrazine yields the network solid [{Cu2(tpypyz)(H2O)2}(Mo5O15)(O3PCH2CH2PO3)]·5.5H2O.

Original languageEnglish (US)
Pages (from-to)1852-1853
Number of pages2
JournalChemical Communications
Volume1
Issue number18
DOIs
StatePublished - 2001

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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