The Effective Surface Area of Amorphous Solid Water Measured by the Infrared Absorption of Carbon Monoxide

Jiao He, Aspen R. Clements, S. M. Emtiaz, Francis Toriello, Robin T. Garrod, Gianfranco Vidali

Research output: Contribution to journalArticle

Abstract

The need to characterize ices coating dust grains in dense interstellar clouds arises from the importance of ice morphology in facilitating the diffusion and storage of radicals and reaction products in ices, a well-known place for the formation of complex molecules. Yet, there is considerable uncertainty about the structure of interstellar medium ices, their ability to store volatiles, and under what conditions. We measured the infrared absorption spectra of CO on the pore surface of porous amorphous solid water (ASW), and quantified the effective pore surface area of ASW. Additionally, we present results obtained from a Monte Carlo model of ASW in which the morphology of the ice is directly visualized and quantified. We found that 200 ML of ASW annealed to 20 K has a total pore surface area that is equivalent to 46 ML. This surface area decreases linearly with temperature to about 120 K. We also found that (1) dangling OH bonds only exist on the surface of pores; (2) almost all of the pores in the ASW are connected to the vacuum-ice interface, and are accessible for adsorption of volatiles from the gas phase; there are few closed cavities inside ASW at least up to a thickness of 200 ML; (3) the total pore surface area is proportional to the total three-coordinated water molecules in the ASW in the temperature range 60-120 K. We also discuss the implications on the structure of ASW and surface reactions in the ice mantle in dense clouds.

Original languageEnglish (US)
Article number94
JournalAstrophysical Journal
Volume878
Issue number2
DOIs
StatePublished - Jun 20 2019

Fingerprint

carbon monoxide
infrared absorption
surface area
ice
water
porosity
absorption spectrum
reaction products
surface reactions
molecules
coating
cavity
Earth mantle
infrared spectra
dust
temperature
vapor phases
mantle
absorption spectra
adsorption

Keywords

  • astrochemistry
  • ISM: molecules
  • methods: laboratory: molecular
  • methods: laboratory: solid state

ASJC Scopus subject areas

  • Astronomy and Astrophysics
  • Space and Planetary Science

Cite this

The Effective Surface Area of Amorphous Solid Water Measured by the Infrared Absorption of Carbon Monoxide. / He, Jiao; Clements, Aspen R.; Emtiaz, S. M.; Toriello, Francis; Garrod, Robin T.; Vidali, Gianfranco.

In: Astrophysical Journal, Vol. 878, No. 2, 94, 20.06.2019.

Research output: Contribution to journalArticle

He, Jiao ; Clements, Aspen R. ; Emtiaz, S. M. ; Toriello, Francis ; Garrod, Robin T. ; Vidali, Gianfranco. / The Effective Surface Area of Amorphous Solid Water Measured by the Infrared Absorption of Carbon Monoxide. In: Astrophysical Journal. 2019 ; Vol. 878, No. 2.
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