The crystallography of π-[carbonyl(triphenylphosphine)platinio]octacarbonyldiiron (2PtFe, 1FeFe)

Ronald Mason, Jon A Zubieta

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Abstract

Three-dimensional X-ray diffractometer data have defined the structure of the title compound. The crystals are monoclinic, space group P21/c, with a 11.88, b 14.13, c 17.49 Å, β 106.9°, Z 4. 1626 independent reflexion intensities (Mo-Kα) formed the basis of the analysis and structure refinement (R1 0.072). The closo-arrangement is based on two PtFe distances of 2.597(5) and 2.530(5) Å and one FeFe bond length of 2.758(8)Å; each iron has four terminal carbonyl ligands, the platinum having terminal carbonyl and triphenylphosphine ligands and a planar stereochemistry.

Original languageEnglish (US)
Pages (from-to)289-294
Number of pages6
JournalJournal of Organometallic Chemistry
Volume66
Issue number2
DOIs
StatePublished - Feb 19 1974
Externally publishedYes

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ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

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