The crystallography of π-[carbonyl(triphenylphosphine)platinio]octacarbonyldiiron (2PtFe, 1FeFe)

Ronald Mason; Jon A. Zubieta

doi:10.1016/S0022-328X(00)91492-X

The crystallography of π-[carbonyl(triphenylphosphine)platinio]octacarbonyldiiron (2PtFe, 1FeFe)

Ronald Mason, Jon A. Zubieta

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Three-dimensional X-ray diffractometer data have defined the structure of the title compound. The crystals are monoclinic, space group P2₁/c, with a 11.88, b 14.13, c 17.49 Å, β 106.9°, Z 4. 1626 independent reflexion intensities (Mo-Kα) formed the basis of the analysis and structure refinement (R₁ 0.072). The closo-arrangement is based on two PtFe distances of 2.597(5) and 2.530(5) Å and one FeFe bond length of 2.758(8)Å; each iron has four terminal carbonyl ligands, the platinum having terminal carbonyl and triphenylphosphine ligands and a planar stereochemistry.

Original language	English (US)
Pages (from-to)	289-294
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	66
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)91492-X
State	Published - Feb 19 1974
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)91492-X

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title = "The crystallography of π-[carbonyl(triphenylphosphine)platinio]octacarbonyldiiron (2PtFe, 1FeFe)",

abstract = "Three-dimensional X-ray diffractometer data have defined the structure of the title compound. The crystals are monoclinic, space group P21/c, with a 11.88, b 14.13, c 17.49 {\AA}, β 106.9°, Z 4. 1626 independent reflexion intensities (Mo-Kα) formed the basis of the analysis and structure refinement (R1 0.072). The closo-arrangement is based on two PtFe distances of 2.597(5) and 2.530(5) {\AA} and one FeFe bond length of 2.758(8){\AA}; each iron has four terminal carbonyl ligands, the platinum having terminal carbonyl and triphenylphosphine ligands and a planar stereochemistry.",

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AU - Zubieta, Jon A.

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AB - Three-dimensional X-ray diffractometer data have defined the structure of the title compound. The crystals are monoclinic, space group P21/c, with a 11.88, b 14.13, c 17.49 Å, β 106.9°, Z 4. 1626 independent reflexion intensities (Mo-Kα) formed the basis of the analysis and structure refinement (R1 0.072). The closo-arrangement is based on two PtFe distances of 2.597(5) and 2.530(5) Å and one FeFe bond length of 2.758(8)Å; each iron has four terminal carbonyl ligands, the platinum having terminal carbonyl and triphenylphosphine ligands and a planar stereochemistry.

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The crystallography of π-[carbonyl(triphenylphosphine)platinio]octacarbonyldiiron (2PtFe, 1FeFe)

Abstract

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