Abstract
The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.
Original language | English (US) |
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Pages (from-to) | 1181-1187 |
Number of pages | 7 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Issue number | 6 |
DOIs | |
State | Published - 1986 |
Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry