The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity

Ian A. Latham, G. Jeffrey Leigh, Christopher J. Pickett, Gottfried Huttner, Ibrahim Jibrill, Jon A Zubieta

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.

Original languageEnglish (US)
Pages (from-to)1181-1187
Number of pages7
JournalJournal of the Chemical Society - Dalton Transactions
Issue number6
DOIs
StatePublished - 1986
Externally publishedYes

Fingerprint

Lewis Acids
Tungsten
Molybdenum
Anions
Nitrogen
Iron
Ligands
pyrimidine-2-thiol
pyrimidine-2-thiolate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity. / Latham, Ian A.; Leigh, G. Jeffrey; Pickett, Christopher J.; Huttner, Gottfried; Jibrill, Ibrahim; Zubieta, Jon A.

In: Journal of the Chemical Society - Dalton Transactions, No. 6, 1986, p. 1181-1187.

Research output: Contribution to journalArticle

Latham, Ian A. ; Leigh, G. Jeffrey ; Pickett, Christopher J. ; Huttner, Gottfried ; Jibrill, Ibrahim ; Zubieta, Jon A. / The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity. In: Journal of the Chemical Society - Dalton Transactions. 1986 ; No. 6. pp. 1181-1187.
@article{c3124f52a090407cb55212a95be15994,
title = "The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity",
abstract = "The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.",
author = "Latham, {Ian A.} and Leigh, {G. Jeffrey} and Pickett, {Christopher J.} and Gottfried Huttner and Ibrahim Jibrill and Zubieta, {Jon A}",
year = "1986",
doi = "10.1039/DT9860001181",
language = "English (US)",
pages = "1181--1187",
journal = "Dalton Transactions",
issn = "0300-9246",
publisher = "Royal Society of Chemistry",
number = "6",

}

TY - JOUR

T1 - The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity

AU - Latham, Ian A.

AU - Leigh, G. Jeffrey

AU - Pickett, Christopher J.

AU - Huttner, Gottfried

AU - Jibrill, Ibrahim

AU - Zubieta, Jon A

PY - 1986

Y1 - 1986

N2 - The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.

AB - The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.

UR - http://www.scopus.com/inward/record.url?scp=37049074559&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049074559&partnerID=8YFLogxK

U2 - 10.1039/DT9860001181

DO - 10.1039/DT9860001181

M3 - Article

AN - SCOPUS:37049074559

SP - 1181

EP - 1187

JO - Dalton Transactions

JF - Dalton Transactions

SN - 0300-9246

IS - 6

ER -