The syntheses and structures of [FeL3]- and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.
|Original language||English (US)|
|Number of pages||7|
|Journal||Journal of the Chemical Society, Dalton Transactions|
|State||Published - Jan 1 1986|
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