Temperature dependence of the electron diffusion coefficient in electrolyte-filled TiO2 nanoparticle films: Evidence against multiple trapping in exponential conduction-band tails

Nikos Kopidakis, Kurt D. Benkstein, Jao Van De Lagemaat, Arthur J. Frank, Quan Yuan, Eric Allan Schiff

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

The temperature and photoexcitation density dependences of the electron transport dynamics in electrolyte-filled mesoporous TiO2 nanoparticle films were investigated by transient photocurrent measurements. The thermal activation energy of the diffusion coefficient of photogenerated electrons ranged from 0.19-0.27 eV, depending on the specific sample studied. The diffusion coefficient also depends strongly on the photoexcitation density; however, the activation energy has little, if any, dependence on the photoexcitation density. The light intensity dependence can be used to infer temperature-independent dispersion parameters in the range 0.3-0.5. These results are inconsistent with the widely used transport model that assumes multiple trapping of electrons in an exponential conduction-band tail. We can also exclude a model allowing for widening of a band tail with increased temperature. Our results suggest that structural, not energetic, disorder limits electron transport in mesoporous TiO2. The analogy between this material and others in which charge transport is limited by structural disorder is discussed.

Original languageEnglish (US)
Article number045326
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume73
Issue number4
DOIs
StatePublished - 2006

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electron diffusion
Photoexcitation
Conduction bands
Electrolytes
conduction bands
diffusion coefficient
photoexcitation
trapping
electrolytes
Nanoparticles
nanoparticles
temperature dependence
Electrons
Activation energy
electrons
disorders
activation energy
Photocurrents
Temperature
Charge transfer

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Temperature dependence of the electron diffusion coefficient in electrolyte-filled TiO2 nanoparticle films : Evidence against multiple trapping in exponential conduction-band tails. / Kopidakis, Nikos; Benkstein, Kurt D.; Van De Lagemaat, Jao; Frank, Arthur J.; Yuan, Quan; Schiff, Eric Allan.

In: Physical Review B - Condensed Matter and Materials Physics, Vol. 73, No. 4, 045326, 2006.

Research output: Contribution to journalArticle

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