Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]•1.5H 2O and of the one-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]

Gundog Yucesan; Vladimir Golub; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.solidstatesciences.2004.10.010

Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]

Gundog Yucesan, Vladimir Golub, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Three different materials of the oxovanadium-ethylenediphosphonate/ copper(II)-bipyridine system [V/O/{(CH ₂) ₂(PO ₃H _x) ₂} ^(4-x)-/Cu(II)(bpy)] were isolated via hydrothermal synthesis from identical starting solutions with temperatures as the only variable. The phases isolated at 120 and 230°C are both two-dimensional networks, [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O (1•1.5H ₂O) and [Cu(bpy)VO(O ₃PCH ₂CH ₂PO ₃)] (3), respectively, while the phase produced at the intermediate temperature of 180°C is the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₅H)] (2). Despite the unexpected absence of correlation between temperature and dimensionality, the number of Cu(II) atoms per 1000 Å ³ increases in the order 2.31:2.57:2.62 for 1:2:3, as expected.

Original language	English (US)
Pages (from-to)	133-139
Number of pages	7
Journal	Solid State Sciences
Volume	7
Issue number	1
DOIs	https://doi.org/10.1016/j.solidstatesciences.2004.10.010
State	Published - Jan 2005

Keywords

Bimetallic oxides
Hydrothermal synthesis
Organic-inorganic hybrid
Vanadophosphonates

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/j.solidstatesciences.2004.10.010

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Yucesan, G., Golub, V., O'Connor, C. J., & Zubieta, J. (2005). Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]. Solid State Sciences, 7(1), 133-139. https://doi.org/10.1016/j.solidstatesciences.2004.10.010

Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]. / Yucesan, Gundog; Golub, Vladimir; O'Connor, Charles J. et al.
In: Solid State Sciences, Vol. 7, No. 1, 01.2005, p. 133-139.

Research output: Contribution to journal › Article › peer-review

Yucesan, G, Golub, V, O'Connor, CJ & Zubieta, J 2005, 'Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]', Solid State Sciences, vol. 7, no. 1, pp. 133-139. https://doi.org/10.1016/j.solidstatesciences.2004.10.010

Yucesan G, Golub V, O'Connor CJ, Zubieta J. Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]. Solid State Sciences. 2005 Jan;7(1):133-139. doi: 10.1016/j.solidstatesciences.2004.10.010

Yucesan, Gundog ; Golub, Vladimir ; O'Connor, Charles J. et al. / Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]•1.5H ₂O and of the one-dimensional [Cu(bpy)VO ₂(O ₃PCH ₂CH ₂PO ₃H)]. In: Solid State Sciences. 2005 ; Vol. 7, No. 1. pp. 133-139.

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title = "Temperature dependence of the crystal chemistry of the oxovanadium- ethylenediphosphonate/copper(II)-2,2′-bipyridine system. Crystal structures of the two-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]•1.5H 2O and of the one-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]",

abstract = "Three different materials of the oxovanadium-ethylenediphosphonate/ copper(II)-bipyridine system [V/O/{(CH 2) 2(PO 3H x) 2} (4-x)-/Cu(II)(bpy)] were isolated via hydrothermal synthesis from identical starting solutions with temperatures as the only variable. The phases isolated at 120 and 230°C are both two-dimensional networks, [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]•1.5H 2O (1•1.5H 2O) and [Cu(bpy)VO(O 3PCH 2CH 2PO 3)] (3), respectively, while the phase produced at the intermediate temperature of 180°C is the one-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 5H)] (2). Despite the unexpected absence of correlation between temperature and dimensionality, the number of Cu(II) atoms per 1000 {\AA} 3 increases in the order 2.31:2.57:2.62 for 1:2:3, as expected.",

keywords = "Bimetallic oxides, Hydrothermal synthesis, Organic-inorganic hybrid, Vanadophosphonates",

author = "Gundog Yucesan and Vladimir Golub and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation (CHE0242153).",

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AU - Yucesan, Gundog

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AU - O'Connor, Charles J.

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N2 - Three different materials of the oxovanadium-ethylenediphosphonate/ copper(II)-bipyridine system [V/O/{(CH 2) 2(PO 3H x) 2} (4-x)-/Cu(II)(bpy)] were isolated via hydrothermal synthesis from identical starting solutions with temperatures as the only variable. The phases isolated at 120 and 230°C are both two-dimensional networks, [Cu(bpy)VO 2(O 3PCH 2CH 2PO 3H)]•1.5H 2O (1•1.5H 2O) and [Cu(bpy)VO(O 3PCH 2CH 2PO 3)] (3), respectively, while the phase produced at the intermediate temperature of 180°C is the one-dimensional [Cu(bpy)VO 2(O 3PCH 2CH 2PO 5H)] (2). Despite the unexpected absence of correlation between temperature and dimensionality, the number of Cu(II) atoms per 1000 Å 3 increases in the order 2.31:2.57:2.62 for 1:2:3, as expected.

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