Tertiary benzylic alcohols react with oxoammonium salts, undergoing a tandem elimination/allylic oxidation to provide an allylic ether product in a single step. This mode of reactivity provides a rapid entry into allylic ethers from certain benzylic tertiary alcohols. The allylic ether may be cleaved under reductive conditions to reveal the allylic alcohol.
|Original language||English (US)|
|Number of pages||4|
|Journal||Organic and Biomolecular Chemistry|
|State||Published - Jul 28 2021|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry