Synthetic Studies of the Nargenicins. Introduction of the C14-C19 side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether

Lucius T. Rossano, Daniel J. Plata, James Kallmerten

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

The stereocontrolled [2,3] Wittig rearrangement of a tertiary allylic ether is employed to establish the remotely functionalized C14-C19 macrolide fragment of an advanced intermediate related to the nargenicin macrolides.

Original languageEnglish (US)
Pages (from-to)5189-5191
Number of pages3
JournalJournal of Organic Chemistry
Volume53
Issue number21
DOIs
StatePublished - Jan 1 1988

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Synthetic Studies of the Nargenicins. Introduction of the C<sub>14</sub>-C<sub>19</sub> side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether'. Together they form a unique fingerprint.

  • Cite this