Synthetic Studies of the Nargenicins. Introduction of the C14-C19 side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether

Lucius T. Rossano; Daniel J. Plata; James Kallmerten

doi:10.1021/jo00256a065

Synthetic Studies of the Nargenicins. Introduction of the C₁₄-C₁₉ side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether

Lucius T. Rossano, Daniel J. Plata, James Kallmerten

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The stereocontrolled [2,3] Wittig rearrangement of a tertiary allylic ether is employed to establish the remotely functionalized C₁₄-C₁₉ macrolide fragment of an advanced intermediate related to the nargenicin macrolides.

Original language	English (US)
Pages (from-to)	5189-5191
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	53
Issue number	21
DOIs	https://doi.org/10.1021/jo00256a065
State	Published - 1988

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1021/jo00256a065

Cite this

@article{bc0f62fcd4384fb6bc80036e9dce68c8,

title = "Synthetic Studies of the Nargenicins. Introduction of the C14-C19 side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether",

abstract = "The stereocontrolled [2,3] Wittig rearrangement of a tertiary allylic ether is employed to establish the remotely functionalized C14-C19 macrolide fragment of an advanced intermediate related to the nargenicin macrolides.",

author = "Rossano, {Lucius T.} and Plata, {Daniel J.} and James Kallmerten",

year = "1988",

doi = "10.1021/jo00256a065",

language = "English (US)",

volume = "53",

pages = "5189--5191",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Synthetic Studies of the Nargenicins. Introduction of the C14-C19 side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether

AU - Rossano, Lucius T.

AU - Plata, Daniel J.

AU - Kallmerten, James

PY - 1988

Y1 - 1988

N2 - The stereocontrolled [2,3] Wittig rearrangement of a tertiary allylic ether is employed to establish the remotely functionalized C14-C19 macrolide fragment of an advanced intermediate related to the nargenicin macrolides.

AB - The stereocontrolled [2,3] Wittig rearrangement of a tertiary allylic ether is employed to establish the remotely functionalized C14-C19 macrolide fragment of an advanced intermediate related to the nargenicin macrolides.

UR - http://www.scopus.com/inward/record.url?scp=0023754039&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0023754039&partnerID=8YFLogxK

U2 - 10.1021/jo00256a065

DO - 10.1021/jo00256a065

M3 - Article

AN - SCOPUS:0023754039

SN - 0022-3263

VL - 53

SP - 5189

EP - 5191

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 21

ER -

Synthetic Studies of the Nargenicins. Introduction of the C₁₄-C₁₉ side chain by diastereoselective [2,3] wittig rearrangement of a tertiary allylic ether

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this