Synthetic studies of the ionophore antibiotic zincophorin. 2. Iterative sigmatropic construction of the C1-C11 subunit

Charles L. Cywin; James Kallmerten

doi:10.1016/S0040-4039(00)77501-0

Synthetic studies of the ionophore antibiotic zincophorin. 2. Iterative sigmatropic construction of the C₁-C₁₁ subunit

Charles L. Cywin, James Kallmerten

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Advanced intermediates 22 and 23, representing the C₁-C₁₁ subunit of the ionophore zincophorin, have been prepared by a scheme incorporating sequential glycolate Claisen and [2,3] Wittig rearrangements to establish the key structural and stereochemical elements of the title compound.

Original language	English (US)
Pages (from-to)	1103-1106
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4039(00)77501-0
State	Published - Feb 12 1993

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)77501-0

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abstract = "Advanced intermediates 22 and 23, representing the C1-C11 subunit of the ionophore zincophorin, have been prepared by a scheme incorporating sequential glycolate Claisen and [2,3] Wittig rearrangements to establish the key structural and stereochemical elements of the title compound.",

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