Synthetic studies of the ionophore antibiotic zincophorin. 2. Iterative sigmatropic construction of the C1-C11 subunit

Charles L. Cywin, James Kallmerten

Research output: Contribution to journalArticle

36 Scopus citations

Abstract

Advanced intermediates 22 and 23, representing the C1-C11 subunit of the ionophore zincophorin, have been prepared by a scheme incorporating sequential glycolate Claisen and [2,3] Wittig rearrangements to establish the key structural and stereochemical elements of the title compound.

Original languageEnglish (US)
Pages (from-to)1103-1106
Number of pages4
JournalTetrahedron Letters
Volume34
Issue number7
DOIs
StatePublished - Feb 12 1993

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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