Synthesis of polypropionate-derived acyclic systems: Diastereoselective hydroboration of highly-functionalized trisubstituted olefins

Lisa D. Coutts; Charles L. Cywin; James Kallmerten

doi:10.1055/s-1993-22576

Synthesis of polypropionate-derived acyclic systems: Diastereoselective hydroboration of highly-functionalized trisubstituted olefins

Lisa D. Coutts, Charles L. Cywin, James Kallmerten

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Hydroboration-oxidation of trisubstituted olefins 2 occurs with exclusive Kishi-Houk stereoselectivity and is accompanied by the stereodependent, collateral cleavage of allylic and homoallylic acetals.

Original language	English (US)
Pages (from-to)	696-698
Number of pages	3
Journal	Synlett
Volume	1993
Issue number	9
DOIs	https://doi.org/10.1055/s-1993-22576
State	Published - Sep 1993

ASJC Scopus subject areas

Organic Chemistry

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@article{5b12eb2028de4db79d6b5ca02935a7f3,

title = "Synthesis of polypropionate-derived acyclic systems: Diastereoselective hydroboration of highly-functionalized trisubstituted olefins",

abstract = "Hydroboration-oxidation of trisubstituted olefins 2 occurs with exclusive Kishi-Houk stereoselectivity and is accompanied by the stereodependent, collateral cleavage of allylic and homoallylic acetals.",

author = "Coutts, {Lisa D.} and Cywin, {Charles L.} and James Kallmerten",

year = "1993",

month = sep,

doi = "10.1055/s-1993-22576",

language = "English (US)",

volume = "1993",

pages = "696--698",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "9",

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T1 - Synthesis of polypropionate-derived acyclic systems

T2 - Diastereoselective hydroboration of highly-functionalized trisubstituted olefins

AU - Coutts, Lisa D.

AU - Cywin, Charles L.

AU - Kallmerten, James

PY - 1993/9

Y1 - 1993/9

N2 - Hydroboration-oxidation of trisubstituted olefins 2 occurs with exclusive Kishi-Houk stereoselectivity and is accompanied by the stereodependent, collateral cleavage of allylic and homoallylic acetals.

AB - Hydroboration-oxidation of trisubstituted olefins 2 occurs with exclusive Kishi-Houk stereoselectivity and is accompanied by the stereodependent, collateral cleavage of allylic and homoallylic acetals.

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U2 - 10.1055/s-1993-22576

DO - 10.1055/s-1993-22576

M3 - Article

AN - SCOPUS:84912961694

SN - 0936-5214

VL - 1993

SP - 696

EP - 698

JO - Synlett

JF - Synlett

IS - 9

ER -

Synthesis of polypropionate-derived acyclic systems: Diastereoselective hydroboration of highly-functionalized trisubstituted olefins

Abstract

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