Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞

Peter J. Rosado, Karin Ruhlandt

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

We present a barium metal-organic framework {[Ba(in)(H2O) 6][in]}∞ prepared via a simple acid-base reaction between BaCO3 and inH (inH = 4-pyridinecarboxylic acid). The complex crystallizes in the monoclinic space group P21/c (a = 6.2592(18), b = 44.289(12), c = 7.2754(15); α=γ= 90, β= 118.890(18); V = 1765.8(8)Å3) displaying an unusual ion association mode with half of the anions metal-bound, whereas the others are associated via a hydrogen-bonded and π⋯π stacking network. Among the coordinated anions, the carboxylate functionalities bridge the metal centers.

Original languageEnglish (US)
Pages (from-to)186-193
Number of pages8
JournalJournal of Coordination Chemistry
Volume64
Issue number1
DOIs
StatePublished - Jan 10 2011

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Crystal structure
Metals
crystal structure
Anions
Negative ions
synthesis
metals
anions
acids
Acids
Barium
carboxylates
barium
Hydrogen
Association reactions
Ions
hydrogen
ions

Keywords

  • Alkaline earth
  • Barium
  • Heavy metal
  • Metal organic frameworks
  • Nitrogen-based ligands

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞. / Rosado, Peter J.; Ruhlandt, Karin.

In: Journal of Coordination Chemistry, Vol. 64, No. 1, 10.01.2011, p. 186-193.

Research output: Contribution to journal › Article

Rosado, PJ & Ruhlandt, K 2011, 'Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞', Journal of Coordination Chemistry, vol. 64, no. 1, pp. 186-193. https://doi.org/10.1080/00958972.2010.538689
Rosado PJ, Ruhlandt K. Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞. Journal of Coordination Chemistry. 2011 Jan 10;64(1):186-193. https://doi.org/10.1080/00958972.2010.538689
Rosado, Peter J. ; Ruhlandt, Karin. / Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞. In: Journal of Coordination Chemistry. 2011 ; Vol. 64, No. 1. pp. 186-193.
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