TY - JOUR
T1 - Synthesis, characterization, and crystal structure of the 3-D metal organic framework {[Ba(in)(H2O)6][in]}∞
AU - Rosado, Peter J.
AU - Ruhlandt-Senge, Karin
N1 - Funding Information:
We gratefully acknowledge support from the National Science Foundation (CHE-0753807). Purchase of the X-ray diffraction equipment was made possible with grants from the National Science Foundation (CHE-9527858), Syracuse University and the WM Keck Foundation. P.J. Rosado thanks the DOE-SCGF (DE-AC05-06OR23100) for a scholarship.
PY - 2011/1/10
Y1 - 2011/1/10
N2 - We present a barium metal-organic framework {[Ba(in)(H2O) 6][in]}∞ prepared via a simple acid-base reaction between BaCO3 and inH (inH = 4-pyridinecarboxylic acid). The complex crystallizes in the monoclinic space group P21/c (a = 6.2592(18), b = 44.289(12), c = 7.2754(15); α=γ= 90, β= 118.890(18); V = 1765.8(8)Å3) displaying an unusual ion association mode with half of the anions metal-bound, whereas the others are associated via a hydrogen-bonded and π⋯π stacking network. Among the coordinated anions, the carboxylate functionalities bridge the metal centers.
AB - We present a barium metal-organic framework {[Ba(in)(H2O) 6][in]}∞ prepared via a simple acid-base reaction between BaCO3 and inH (inH = 4-pyridinecarboxylic acid). The complex crystallizes in the monoclinic space group P21/c (a = 6.2592(18), b = 44.289(12), c = 7.2754(15); α=γ= 90, β= 118.890(18); V = 1765.8(8)Å3) displaying an unusual ion association mode with half of the anions metal-bound, whereas the others are associated via a hydrogen-bonded and π⋯π stacking network. Among the coordinated anions, the carboxylate functionalities bridge the metal centers.
KW - Alkaline earth
KW - Barium
KW - Heavy metal
KW - Metal organic frameworks
KW - Nitrogen-based ligands
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U2 - 10.1080/00958972.2010.538689
DO - 10.1080/00958972.2010.538689
M3 - Article
AN - SCOPUS:78951482844
SN - 0095-8972
VL - 64
SP - 186
EP - 193
JO - Journal of Coordination Chemistry
JF - Journal of Coordination Chemistry
IS - 1
ER -