TY - JOUR
T1 - Synthesis and X-ray structural characterization of [Me4n]3([(SCH2CH2s)Mos3]2Fe), the first example of a heteronuclear trimer containing molybdenum in a square-pyramidal geometry
AU - Dahlstrom, Phillip L.
AU - Kumar, Surendra
AU - Zubieta, Jon
PY - 1981
Y1 - 1981
N2 - Reaction of a mixture of (NH4)2MoS4 and disodium ethane-1,2-dithiolate in dimethylformamide- MeCN with a methanolic solution of anhydrous FeCl3, followed by the addition of Me4NBr, gives the trinuclear complex [Me4N]3([(SCH2CH2S)MoS3]2Fe), an X-ray crystal structure of which shows the molybdenum atoms to have distorted square-pyramidal geometry and the iron atom to be tetrahedrally co-ordinated to four µ- sulphido-lieands.
AB - Reaction of a mixture of (NH4)2MoS4 and disodium ethane-1,2-dithiolate in dimethylformamide- MeCN with a methanolic solution of anhydrous FeCl3, followed by the addition of Me4NBr, gives the trinuclear complex [Me4N]3([(SCH2CH2S)MoS3]2Fe), an X-ray crystal structure of which shows the molybdenum atoms to have distorted square-pyramidal geometry and the iron atom to be tetrahedrally co-ordinated to four µ- sulphido-lieands.
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U2 - 10.1039/C39810000411
DO - 10.1039/C39810000411
M3 - Article
AN - SCOPUS:37049103488
SN - 0022-4936
SP - 411
EP - 412
JO - Journal of the Chemical Society - Series Chemical Communications
JF - Journal of the Chemical Society - Series Chemical Communications
IS - 9
ER -