Synthesis and Structure of Cs[(VO)2(OH)(O3PCH2CH2PO 3)]: A Two-Dimensional Solid with Pillared Layers

Grant H. Bonavia, Robert C. Haushalter, Sichu Lu, Charles J. O'Conner, Jon Zubieta

Research output: Contribution to journalArticle

32 Scopus citations

Abstract

The title compound Cs[(VO)2(OH)(O3PCH2CH2PO 3)] 1 was synthesized hydrothermally from a mixture of CsVO3, H2O3PCH2CH2PO3H 2, and H2O in the mole ratio 1 : 1.22 : 535 and heated to 200°C for 48 hr. Phosphonate 1 is formed in 45% yield and crystallizes in the monoclinic space group P21/c witha=11.798(2) Å,b=11.056(2) Å,c=8.682(2) Å,β=104.92(3)°,V=1094.3(4) Å3,Z=4, andR=0.054. The framework consists of complimentary inorganic V/P/O layers joined by ethylenediphosphonate ligands, creating an inorganic bilayer. The bilayers are seperated by an interlamellar region of Cs+cations. There are two unique VO5square pyramids from which the inorganic V/P/O layers are constructed.

Original languageEnglish (US)
Pages (from-to)144-150
Number of pages7
JournalJournal of Solid State Chemistry
Volume132
Issue number1
DOIs
StatePublished - Aug 1 1997

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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