Synthesis and Structure of Cs[(VO)2(OH)(O3PCH2CH2PO 3)]: A Two-Dimensional Solid with Pillared Layers

Grant H. Bonavia; Robert C. Haushalter; Sichu Lu; Charles J. O'Conner; Jon Zubieta

doi:10.1006/jssc.1997.7433

Synthesis and Structure of Cs[(VO)₂(OH)(O₃PCH₂CH₂PO ₃)]: A Two-Dimensional Solid with Pillared Layers

Grant H. Bonavia, Robert C. Haushalter, Sichu Lu, Charles J. O'Conner, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The title compound Cs[(VO)₂(OH)(O₃PCH₂CH₂PO ₃)] 1 was synthesized hydrothermally from a mixture of CsVO₃, H₂O₃PCH₂CH₂PO₃H ₂, and H₂O in the mole ratio 1 : 1.22 : 535 and heated to 200°C for 48 hr. Phosphonate 1 is formed in 45% yield and crystallizes in the monoclinic space group P2₁/c witha=11.798(2) Å,b=11.056(2) Å,c=8.682(2) Å,β=104.92(3)°,V=1094.3(4) Å³,Z=4, andR=0.054. The framework consists of complimentary inorganic V/P/O layers joined by ethylenediphosphonate ligands, creating an inorganic bilayer. The bilayers are seperated by an interlamellar region of Cs⁺cations. There are two unique VO₅square pyramids from which the inorganic V/P/O layers are constructed.

Original language	English (US)
Pages (from-to)	144-150
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	132
Issue number	1
DOIs	https://doi.org/10.1006/jssc.1997.7433
State	Published - Aug 1997

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis and Structure of Cs[(VO)2(OH)(O3PCH2CH2PO 3)]: A Two-Dimensional Solid with Pillared Layers",

abstract = "The title compound Cs[(VO)2(OH)(O3PCH2CH2PO 3)] 1 was synthesized hydrothermally from a mixture of CsVO3, H2O3PCH2CH2PO3H 2, and H2O in the mole ratio 1 : 1.22 : 535 and heated to 200°C for 48 hr. Phosphonate 1 is formed in 45% yield and crystallizes in the monoclinic space group P21/c witha=11.798(2) {\AA},b=11.056(2) {\AA},c=8.682(2) {\AA},β=104.92(3)°,V=1094.3(4) {\AA}3,Z=4, andR=0.054. The framework consists of complimentary inorganic V/P/O layers joined by ethylenediphosphonate ligands, creating an inorganic bilayer. The bilayers are seperated by an interlamellar region of Cs+cations. There are two unique VO5square pyramids from which the inorganic V/P/O layers are constructed.",

author = "Bonavia, {Grant H.} and Haushalter, {Robert C.} and Sichu Lu and O'Conner, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was funded by a grant from the National Science Foundation, CHE9617232.",

year = "1997",

month = aug,

doi = "10.1006/jssc.1997.7433",

language = "English (US)",

volume = "132",

pages = "144--150",

journal = "Journal of Solid State Chemistry",

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T1 - Synthesis and Structure of Cs[(VO)2(OH)(O3PCH2CH2PO 3)]

T2 - A Two-Dimensional Solid with Pillared Layers

AU - Bonavia, Grant H.

AU - Haushalter, Robert C.

AU - Lu, Sichu

AU - O'Conner, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was funded by a grant from the National Science Foundation, CHE9617232.

PY - 1997/8

Y1 - 1997/8

N2 - The title compound Cs[(VO)2(OH)(O3PCH2CH2PO 3)] 1 was synthesized hydrothermally from a mixture of CsVO3, H2O3PCH2CH2PO3H 2, and H2O in the mole ratio 1 : 1.22 : 535 and heated to 200°C for 48 hr. Phosphonate 1 is formed in 45% yield and crystallizes in the monoclinic space group P21/c witha=11.798(2) Å,b=11.056(2) Å,c=8.682(2) Å,β=104.92(3)°,V=1094.3(4) Å3,Z=4, andR=0.054. The framework consists of complimentary inorganic V/P/O layers joined by ethylenediphosphonate ligands, creating an inorganic bilayer. The bilayers are seperated by an interlamellar region of Cs+cations. There are two unique VO5square pyramids from which the inorganic V/P/O layers are constructed.

AB - The title compound Cs[(VO)2(OH)(O3PCH2CH2PO 3)] 1 was synthesized hydrothermally from a mixture of CsVO3, H2O3PCH2CH2PO3H 2, and H2O in the mole ratio 1 : 1.22 : 535 and heated to 200°C for 48 hr. Phosphonate 1 is formed in 45% yield and crystallizes in the monoclinic space group P21/c witha=11.798(2) Å,b=11.056(2) Å,c=8.682(2) Å,β=104.92(3)°,V=1094.3(4) Å3,Z=4, andR=0.054. The framework consists of complimentary inorganic V/P/O layers joined by ethylenediphosphonate ligands, creating an inorganic bilayer. The bilayers are seperated by an interlamellar region of Cs+cations. There are two unique VO5square pyramids from which the inorganic V/P/O layers are constructed.

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DO - 10.1006/jssc.1997.7433

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Synthesis and Structure of Cs[(VO)₂(OH)(O₃PCH₂CH₂PO ₃)]: A Two-Dimensional Solid with Pillared Layers

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