Synthesis and structural characterization of the yttrium(III)-polyalcohol complexes: [Y{(HOCH2)3CCH3}2Cl2]Cl · MeOH, [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl and [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2

Qin Chen; Yuan Da Chang; Jon Zubieta

doi:10.1016/s0020-1693(96)05514-4

Synthesis and structural characterization of the yttrium(III)-polyalcohol complexes: [Y{(HOCH₂)₃CCH₃}₂Cl₂]Cl · MeOH, [Y{(HOCH₂)₃CN(CH₂CH₂OH) ₂}Cl₂(MeOH)]Cl and [Y{(HOCH₂)₃CCH₃}₂(NO ₃)(H2O)](NO3)₂

Qin Chen, Yuan Da Chang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The reactions of YCl₃ with the polyalcohols (HOCH₂)₃CCH₃ and (HOCH₂)₃CN(CH₂CH₂OH)₂ in MeOH yielded [Y{(HOCH_2- O₃CCH₃}₂Cl₂]Cl · MeOH (1) and [Y{(HOCH₂)₃CN(CH₂CH₂OH) ₂}Cl₂(MeOH)]Cl (2), respectively. Similarly, the reaction ofY(NO₃)₃ with (HOCH₂)₃CCH₃ in ethanol gave [Y{(HOCH₂)₃CCH₃}₂(NO ₃)(H₂O)](NO₃)₂ (3). In all cases, the ligands are present in the alcohol form rather than the alkoxy form. Crystal data: C₁₁H₂₈O₇Cl₃Y (1): orthorhombic Pna2₁, a = 9.218(1), b = 23.501(3), c = 9.222(1) Å, V = 1997.8(9) Å³, Z = 4. C₉H₂₃O₆NCl₃Y (2), triclinic P1, a = 8.859(3), b = 14.336(4), c = 6.975(2) Å, a = 103.85(1), β = 105.02(2), γ = 96.10(2)°, V = 817.3(4) Å³, Z = 2; C₁₀H₂₆O₁₆N₃Y, monoclinic P2₁/c, a = 9.354(2), b = 11.750(3), c = 19.7211(4) Å, β = 95.87(1)°, V = 2156.2(9) Å³, Z = 4.

Original language	English (US)
Pages (from-to)	257-262
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	258
Issue number	2
DOIs	https://doi.org/10.1016/s0020-1693(96)05514-4
State	Published - May 30 1997

Keywords

Crystal structures
Polyalcohol complexes
Yttrium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/s0020-1693(96)05514-4

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Synthesis and structural characterization of the yttrium(III)-polyalcohol complexes: [Y{(HOCH₂)₃CCH₃}₂Cl₂]Cl · MeOH, [Y{(HOCH₂)₃CN(CH₂CH₂OH) ₂}Cl₂(MeOH)]Cl and [Y{(HOCH₂)₃CCH₃}₂(NO ₃)(H2O)](NO3)₂. / Chen, Qin; Chang, Yuan Da; Zubieta, Jon.
In: Inorganica Chimica Acta, Vol. 258, No. 2, 30.05.1997, p. 257-262.

Research output: Contribution to journal › Article › peer-review

@article{d2f19e8adf7b42fca0ee2a0fde8d7c39,

title = "Synthesis and structural characterization of the yttrium(III)-polyalcohol complexes: [Y{(HOCH2)3CCH3}2Cl2]Cl · MeOH, [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl and [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2",

abstract = "The reactions of YCl3 with the polyalcohols (HOCH2)3CCH3 and (HOCH2)3CN(CH2CH2OH)2 in MeOH yielded [Y{(HOCH2- O3CCH3}2Cl2]Cl · MeOH (1) and [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl (2), respectively. Similarly, the reaction ofY(NO3)3 with (HOCH2)3CCH3 in ethanol gave [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2 (3). In all cases, the ligands are present in the alcohol form rather than the alkoxy form. Crystal data: C11H28O7Cl3Y (1): orthorhombic Pna21, a = 9.218(1), b = 23.501(3), c = 9.222(1) {\AA}, V = 1997.8(9) {\AA}3, Z = 4. C9H23O6NCl3Y (2), triclinic P1, a = 8.859(3), b = 14.336(4), c = 6.975(2) {\AA}, a = 103.85(1), β = 105.02(2), γ = 96.10(2)°, V = 817.3(4) {\AA}3, Z = 2; C10H26O16N3Y, monoclinic P21/c, a = 9.354(2), b = 11.750(3), c = 19.7211(4) {\AA}, β = 95.87(1)°, V = 2156.2(9) {\AA}3, Z = 4.",

keywords = "Crystal structures, Polyalcohol complexes, Yttrium complexes",

author = "Qin Chen and Chang, {Yuan Da} and Jon Zubieta",

note = "Funding Information: This work was supported by grant DE-FG02-93ER6157 1 from the Department of Energy, Medical Applications and Biophysical Research Division.",

year = "1997",

month = may,

day = "30",

doi = "10.1016/s0020-1693(96)05514-4",

language = "English (US)",

volume = "258",

pages = "257--262",

journal = "Inorganica Chimica Acta",

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publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Synthesis and structural characterization of the yttrium(III)-polyalcohol complexes

T2 - [Y{(HOCH2)3CCH3}2Cl2]Cl · MeOH, [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl and [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2

AU - Chen, Qin

AU - Chang, Yuan Da

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by grant DE-FG02-93ER6157 1 from the Department of Energy, Medical Applications and Biophysical Research Division.

PY - 1997/5/30

Y1 - 1997/5/30

N2 - The reactions of YCl3 with the polyalcohols (HOCH2)3CCH3 and (HOCH2)3CN(CH2CH2OH)2 in MeOH yielded [Y{(HOCH2- O3CCH3}2Cl2]Cl · MeOH (1) and [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl (2), respectively. Similarly, the reaction ofY(NO3)3 with (HOCH2)3CCH3 in ethanol gave [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2 (3). In all cases, the ligands are present in the alcohol form rather than the alkoxy form. Crystal data: C11H28O7Cl3Y (1): orthorhombic Pna21, a = 9.218(1), b = 23.501(3), c = 9.222(1) Å, V = 1997.8(9) Å3, Z = 4. C9H23O6NCl3Y (2), triclinic P1, a = 8.859(3), b = 14.336(4), c = 6.975(2) Å, a = 103.85(1), β = 105.02(2), γ = 96.10(2)°, V = 817.3(4) Å3, Z = 2; C10H26O16N3Y, monoclinic P21/c, a = 9.354(2), b = 11.750(3), c = 19.7211(4) Å, β = 95.87(1)°, V = 2156.2(9) Å3, Z = 4.

AB - The reactions of YCl3 with the polyalcohols (HOCH2)3CCH3 and (HOCH2)3CN(CH2CH2OH)2 in MeOH yielded [Y{(HOCH2- O3CCH3}2Cl2]Cl · MeOH (1) and [Y{(HOCH2)3CN(CH2CH2OH) 2}Cl2(MeOH)]Cl (2), respectively. Similarly, the reaction ofY(NO3)3 with (HOCH2)3CCH3 in ethanol gave [Y{(HOCH2)3CCH3}2(NO 3)(H2O)](NO3)2 (3). In all cases, the ligands are present in the alcohol form rather than the alkoxy form. Crystal data: C11H28O7Cl3Y (1): orthorhombic Pna21, a = 9.218(1), b = 23.501(3), c = 9.222(1) Å, V = 1997.8(9) Å3, Z = 4. C9H23O6NCl3Y (2), triclinic P1, a = 8.859(3), b = 14.336(4), c = 6.975(2) Å, a = 103.85(1), β = 105.02(2), γ = 96.10(2)°, V = 817.3(4) Å3, Z = 2; C10H26O16N3Y, monoclinic P21/c, a = 9.354(2), b = 11.750(3), c = 19.7211(4) Å, β = 95.87(1)°, V = 2156.2(9) Å3, Z = 4.

KW - Crystal structures

KW - Polyalcohol complexes

KW - Yttrium complexes

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