Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me3C6H2)2(OEt2)], [Be{O(2,4,6-t-Bu3C6H2)}2(OEt2)], and [Be{S(2,4,6-t-Bu3C6H2)}2(THF)]·PhMe and Determination of the Structure of [BeCl2(OEt2)2]

Karin Ruhlandt-Senge; Ruth A. Bartlett; Marilyn M. Olmstead; Philip P. Power

doi:10.1021/ic00061a031

Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me₃C₆H₂)₂(OEt₂)], [Be{O(2,4,6-t-Bu₃C₆H₂)}₂(OEt₂)], and [Be{S(2,4,6-t-Bu₃C₆H₂)}₂(THF)]·PhMe and Determination of the Structure of [BeCl₂(OEt₂)₂]

Karin Ruhlandt-Senge, Ruth A. Bartlett, Marilyn M. Olmstead, Philip P. Power

Research output: Contribution to journal › Article › peer-review

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Abstract

The preparations of some new classes of beryllium compounds that have a coordination number of 3 at beryllium are reported. They were synthesized by the reaction of BeCl₂(OEt₂)₂ with the appropriate lithium salt to give the products [BeMes₂(OEt₂)] (1; Mes = 2,4,6-Me₃C₆H₂), [Be(OMes*)₂(OEt₂)] (2; Mes* = 2,4,6-t-Bu₃C₆H₂), and [Be(SMes*)₂(THF)]·PhMe (3). The compounds were characterized by ¹H NMR and IR spectroscopy, C and H analysis, and X-ray crystallography. The crystal structure of [BeCl₂(OEt₂)₂] (4) was also determined. Crystal data (Mo Kα (λ = 0.710 69 Å) at 130 K) are as follows: [BeMes₂(OEt₂)] (1), a = 11.913(3) Å, c = 28.390(8) Å, V = 4029(2) Å³, tetragonal, space group [formula omitted], 975 (I > 3σ(I)) data, R = 0.042; [Be(OMes*)₂OEt₂] (2), a = 25.022(9) Å, b = 9.834(3) Å, c = 16.290(4) Å, β = 96.48(3)°, V = 3982(2) Å³, monoclinic, space group C2/c, 3173 (I > 3σ(I)) data, R = 0.051; [Be(SMes*)₂THF]·PhMe (3), a = 8.695(4) Å, b = 17.399(10) Å, c = 17.437(8) Å, α = 60.80(4)°, β = 83.29(4)°, γ = 84.24(4)°, V = 2284(2) Å³, triclinic, space group [formula omitted], 3751 (I > 2σ(I)) data, R = 0.061; [BeCl₂(OEt₂)₂] (4), a = 7.486(3) Å, c = 20.022(8) Å, V = 971.7(6) Å³, trigonal, space group P3₁2₁, 646 (I > 2σ(I)) data, R = 0.028.

Original language	English (US)
Pages (from-to)	1724-1728
Number of pages	5
Journal	Inorganic Chemistry
Volume	32
Issue number	9
DOIs	https://doi.org/10.1021/ic00061a031
State	Published - 1993
Externally published	Yes

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Physical and Theoretical Chemistry
Inorganic Chemistry

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Ruhlandt-Senge, K., Bartlett, R. A., Olmstead, M. M., & Power, P. P. (1993). Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me₃C₆H₂)₂(OEt₂)], [Be{O(2,4,6-t-Bu₃C₆H₂)}₂(OEt₂)], and [Be{S(2,4,6-t-Bu₃C₆H₂)}₂(THF)]·PhMe and Determination of the Structure of [BeCl₂(OEt₂)₂]. Inorganic Chemistry, 32(9), 1724-1728. https://doi.org/10.1021/ic00061a031

Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me₃C₆H₂)₂(OEt₂)], [Be{O(2,4,6-t-Bu₃C₆H₂)}₂(OEt₂)], and [Be{S(2,4,6-t-Bu₃C₆H₂)}₂(THF)]·PhMe and Determination of the Structure of [BeCl₂(OEt₂)₂]. / Ruhlandt-Senge, Karin; Bartlett, Ruth A.; Olmstead, Marilyn M. et al.
In: Inorganic Chemistry, Vol. 32, No. 9, 1993, p. 1724-1728.

Research output: Contribution to journal › Article › peer-review

Ruhlandt-Senge, K, Bartlett, RA, Olmstead, MM & Power, PP 1993, 'Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me₃C₆H₂)₂(OEt₂)], [Be{O(2,4,6-t-Bu₃C₆H₂)}₂(OEt₂)], and [Be{S(2,4,6-t-Bu₃C₆H₂)}₂(THF)]·PhMe and Determination of the Structure of [BeCl₂(OEt₂)₂]', Inorganic Chemistry, vol. 32, no. 9, pp. 1724-1728. https://doi.org/10.1021/ic00061a031

@article{73aaf40735c14fa88294ca4c19f43647,

title = "Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me3C6H2)2(OEt2)], [Be{O(2,4,6-t-Bu3C6H2)}2(OEt2)], and [Be{S(2,4,6-t-Bu3C6H2)}2(THF)]·PhMe and Determination of the Structure of [BeCl2(OEt2)2]",

abstract = "The preparations of some new classes of beryllium compounds that have a coordination number of 3 at beryllium are reported. They were synthesized by the reaction of BeCl2(OEt2)2 with the appropriate lithium salt to give the products [BeMes2(OEt2)] (1; Mes = 2,4,6-Me3C6H2), [Be(OMes*)2(OEt2)] (2; Mes* = 2,4,6-t-Bu3C6H2), and [Be(SMes*)2(THF)]·PhMe (3). The compounds were characterized by 1H NMR and IR spectroscopy, C and H analysis, and X-ray crystallography. The crystal structure of [BeCl2(OEt2)2] (4) was also determined. Crystal data (Mo Kα (λ = 0.710 69 {\AA}) at 130 K) are as follows: [BeMes2(OEt2)] (1), a = 11.913(3) {\AA}, c = 28.390(8) {\AA}, V = 4029(2) {\AA}3, tetragonal, space group [formula omitted], 975 (I > 3σ(I)) data, R = 0.042; [Be(OMes*)2OEt2] (2), a = 25.022(9) {\AA}, b = 9.834(3) {\AA}, c = 16.290(4) {\AA}, β = 96.48(3)°, V = 3982(2) {\AA}3, monoclinic, space group C2/c, 3173 (I > 3σ(I)) data, R = 0.051; [Be(SMes*)2THF]·PhMe (3), a = 8.695(4) {\AA}, b = 17.399(10) {\AA}, c = 17.437(8) {\AA}, α = 60.80(4)°, β = 83.29(4)°, γ = 84.24(4)°, V = 2284(2) {\AA}3, triclinic, space group [formula omitted], 3751 (I > 2σ(I)) data, R = 0.061; [BeCl2(OEt2)2] (4), a = 7.486(3) {\AA}, c = 20.022(8) {\AA}, V = 971.7(6) {\AA}3, trigonal, space group P3121, 646 (I > 2σ(I)) data, R = 0.028.",

author = "Karin Ruhlandt-Senge and Bartlett, {Ruth A.} and Olmstead, {Marilyn M.} and Power, {Philip P.}",

year = "1993",

doi = "10.1021/ic00061a031",

language = "English (US)",

volume = "32",

pages = "1724--1728",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Synthesis and Structural Characterization of the Beryllium Compounds [Be(2,4,6-Me3C6H2)2(OEt2)], [Be{O(2,4,6-t-Bu3C6H2)}2(OEt2)], and [Be{S(2,4,6-t-Bu3C6H2)}2(THF)]·PhMe and Determination of the Structure of [BeCl2(OEt2)2]

AU - Ruhlandt-Senge, Karin

AU - Bartlett, Ruth A.

AU - Olmstead, Marilyn M.

AU - Power, Philip P.

PY - 1993

Y1 - 1993

N2 - The preparations of some new classes of beryllium compounds that have a coordination number of 3 at beryllium are reported. They were synthesized by the reaction of BeCl2(OEt2)2 with the appropriate lithium salt to give the products [BeMes2(OEt2)] (1; Mes = 2,4,6-Me3C6H2), [Be(OMes*)2(OEt2)] (2; Mes* = 2,4,6-t-Bu3C6H2), and [Be(SMes*)2(THF)]·PhMe (3). The compounds were characterized by 1H NMR and IR spectroscopy, C and H analysis, and X-ray crystallography. The crystal structure of [BeCl2(OEt2)2] (4) was also determined. Crystal data (Mo Kα (λ = 0.710 69 Å) at 130 K) are as follows: [BeMes2(OEt2)] (1), a = 11.913(3) Å, c = 28.390(8) Å, V = 4029(2) Å3, tetragonal, space group [formula omitted], 975 (I > 3σ(I)) data, R = 0.042; [Be(OMes*)2OEt2] (2), a = 25.022(9) Å, b = 9.834(3) Å, c = 16.290(4) Å, β = 96.48(3)°, V = 3982(2) Å3, monoclinic, space group C2/c, 3173 (I > 3σ(I)) data, R = 0.051; [Be(SMes*)2THF]·PhMe (3), a = 8.695(4) Å, b = 17.399(10) Å, c = 17.437(8) Å, α = 60.80(4)°, β = 83.29(4)°, γ = 84.24(4)°, V = 2284(2) Å3, triclinic, space group [formula omitted], 3751 (I > 2σ(I)) data, R = 0.061; [BeCl2(OEt2)2] (4), a = 7.486(3) Å, c = 20.022(8) Å, V = 971.7(6) Å3, trigonal, space group P3121, 646 (I > 2σ(I)) data, R = 0.028.

AB - The preparations of some new classes of beryllium compounds that have a coordination number of 3 at beryllium are reported. They were synthesized by the reaction of BeCl2(OEt2)2 with the appropriate lithium salt to give the products [BeMes2(OEt2)] (1; Mes = 2,4,6-Me3C6H2), [Be(OMes*)2(OEt2)] (2; Mes* = 2,4,6-t-Bu3C6H2), and [Be(SMes*)2(THF)]·PhMe (3). The compounds were characterized by 1H NMR and IR spectroscopy, C and H analysis, and X-ray crystallography. The crystal structure of [BeCl2(OEt2)2] (4) was also determined. Crystal data (Mo Kα (λ = 0.710 69 Å) at 130 K) are as follows: [BeMes2(OEt2)] (1), a = 11.913(3) Å, c = 28.390(8) Å, V = 4029(2) Å3, tetragonal, space group [formula omitted], 975 (I > 3σ(I)) data, R = 0.042; [Be(OMes*)2OEt2] (2), a = 25.022(9) Å, b = 9.834(3) Å, c = 16.290(4) Å, β = 96.48(3)°, V = 3982(2) Å3, monoclinic, space group C2/c, 3173 (I > 3σ(I)) data, R = 0.051; [Be(SMes*)2THF]·PhMe (3), a = 8.695(4) Å, b = 17.399(10) Å, c = 17.437(8) Å, α = 60.80(4)°, β = 83.29(4)°, γ = 84.24(4)°, V = 2284(2) Å3, triclinic, space group [formula omitted], 3751 (I > 2σ(I)) data, R = 0.061; [BeCl2(OEt2)2] (4), a = 7.486(3) Å, c = 20.022(8) Å, V = 971.7(6) Å3, trigonal, space group P3121, 646 (I > 2σ(I)) data, R = 0.028.

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