TY - JOUR
T1 - Synthesis and structural characterization of rhenium(I) tricarbonyl complexes with the bidentate ligands o-(diphenylphosphino)benzaldehyde (P ∩ O) and o-[(diphenylphosphino)benzylidene]analine (P ∩ N)
AU - Chen, Xiaoyuan
AU - Femia, Frank J.
AU - Babich, John W.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by a grant from the Department of Energy (DOE), Office of Health and Environmental Research D2-FG02-99ER62791.
PY - 2001/4/27
Y1 - 2001/4/27
N2 - A series of rhenium(I) tricarbonyl complexes with bidentate P,O donor ligand o-(diphenylphosphino)benzaldehyde (P ∩ O) and its Schiff base P,N donor ligand o-[diphenylphosphino)benzylidene]analine (P ∩ N) have been synthesized and structurally characterized. All the complexes of the type [ReX(CO)3(LL)] (where LL = P ∩ O, P ∩ N) reveal a distorted octahedral structure with the three carbonyl ligands arranged in the facial fashion. Crystal data for 1, C22H15ClO4PRe·1/2C6 H14: triclinic, P1, a = 8.7430(4), b = 9.5767(4), c = 13.9449(6) Å, α = 93.651(1), β = 101.265(1), γ = 93.048(1); V = 1140.20(9) Å3, Z = 2.2, C22H15BrO4Pre: monoclinic, C2/c, a = 31.6800(16), b = 8.8880(4), c = 18.4517(9) Å, β = 124.990(1); V = 4256.4(4) Å3, Z = 8. 3, C28H20ClNO3Pre: monoclinic, C2/c, a = 22.675(4), b = 8.803(2), c = 28.218(5) Å, β = 100.192(3); V = 5543.5(16) Å3, Z = 8.4, C28H20BrNO3Pre: monoclinic, C2/c, a = 23.035(1), b = 8.7561(4), c = 28.269(1) Å, β = 100.811(1); V = 5600.4(5) Å3, Z = 8.
AB - A series of rhenium(I) tricarbonyl complexes with bidentate P,O donor ligand o-(diphenylphosphino)benzaldehyde (P ∩ O) and its Schiff base P,N donor ligand o-[diphenylphosphino)benzylidene]analine (P ∩ N) have been synthesized and structurally characterized. All the complexes of the type [ReX(CO)3(LL)] (where LL = P ∩ O, P ∩ N) reveal a distorted octahedral structure with the three carbonyl ligands arranged in the facial fashion. Crystal data for 1, C22H15ClO4PRe·1/2C6 H14: triclinic, P1, a = 8.7430(4), b = 9.5767(4), c = 13.9449(6) Å, α = 93.651(1), β = 101.265(1), γ = 93.048(1); V = 1140.20(9) Å3, Z = 2.2, C22H15BrO4Pre: monoclinic, C2/c, a = 31.6800(16), b = 8.8880(4), c = 18.4517(9) Å, β = 124.990(1); V = 4256.4(4) Å3, Z = 8. 3, C28H20ClNO3Pre: monoclinic, C2/c, a = 22.675(4), b = 8.803(2), c = 28.218(5) Å, β = 100.192(3); V = 5543.5(16) Å3, Z = 8.4, C28H20BrNO3Pre: monoclinic, C2/c, a = 23.035(1), b = 8.7561(4), c = 28.269(1) Å, β = 100.811(1); V = 5600.4(5) Å3, Z = 8.
KW - Bidentate P,O donor ligand
KW - P,N donor ligand
KW - Rhenium(I) complexes
KW - Tricarbonyl complexes
KW - X-ray crystal structure
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U2 - 10.1016/S0020-1693(01)00302-4
DO - 10.1016/S0020-1693(01)00302-4
M3 - Article
AN - SCOPUS:0035957786
SN - 0020-1693
VL - 315
SP - 147
EP - 152
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 2
ER -