Synthesis and structural characterization of [Cu(SC6H 4-o-SiMe3)]12, an unusual example of a 'paddle-wheel' dodecametallic thiolate cluster

Eric Block; Michael Gernon; Hyunkyu Kang; Shuncheng Liu; Jon Zubieta

doi:10.1039/C39880001031

Synthesis and structural characterization of [Cu(SC₆H ₄-o-SiMe₃)]₁₂, an unusual example of a 'paddle-wheel' dodecametallic thiolate cluster

Eric Block, Michael Gernon, Hyunkyu Kang, Shuncheng Liu, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Treatment of [Cu(MeCN)₄]PF₆ with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC ₆H₄-o-SiMe₃, affords red-orange crystals of [Cu(SC₆H₄-o-SiMe₃)]₁₂, a dodecametallic thiolate cluster with a 'paddle-wheel' C₁₂S ₁₂ core.

Original language	English (US)
Pages (from-to)	1031-1033
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39880001031
State	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Synthesis and structural characterization of [Cu(SC6H 4-o-SiMe3)]12, an unusual example of a 'paddle-wheel' dodecametallic thiolate cluster",

abstract = "Treatment of [Cu(MeCN)4]PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC 6H4-o-SiMe3, affords red-orange crystals of [Cu(SC6H4-o-SiMe3)]12, a dodecametallic thiolate cluster with a 'paddle-wheel' C12S 12 core.",

author = "Eric Block and Michael Gernon and Hyunkyu Kang and Shuncheng Liu and Jon Zubieta",

year = "1988",

doi = "10.1039/C39880001031",

language = "English (US)",

pages = "1031--1033",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

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T1 - Synthesis and structural characterization of [Cu(SC6H 4-o-SiMe3)]12, an unusual example of a 'paddle-wheel' dodecametallic thiolate cluster

AU - Block, Eric

AU - Gernon, Michael

AU - Kang, Hyunkyu

AU - Liu, Shuncheng

AU - Zubieta, Jon

PY - 1988

Y1 - 1988

N2 - Treatment of [Cu(MeCN)4]PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC 6H4-o-SiMe3, affords red-orange crystals of [Cu(SC6H4-o-SiMe3)]12, a dodecametallic thiolate cluster with a 'paddle-wheel' C12S 12 core.

AB - Treatment of [Cu(MeCN)4]PF6 with the sterically-hindered thiolate ligand 2-(trimethylsilyl)benzenethiol, HSC 6H4-o-SiMe3, affords red-orange crystals of [Cu(SC6H4-o-SiMe3)]12, a dodecametallic thiolate cluster with a 'paddle-wheel' C12S 12 core.

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U2 - 10.1039/C39880001031

DO - 10.1039/C39880001031

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JF - Chemical Communications

IS - 15

ER -

Synthesis and structural characterization of [Cu(SC₆H ₄-o-SiMe₃)]₁₂, an unusual example of a 'paddle-wheel' dodecametallic thiolate cluster

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