Synthesis and structural characterization of cis and trans [MoCl4(H2NBut)2]

Shuncheng Liu; Jon Zubieta

doi:10.1016/S0020-1693(00)88015-9

Synthesis and structural characterization of cis and trans [MoCl₄(H₂NBu^t)₂]

Shuncheng Liu, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The reaction of [MoCl₄(PPh₃)₂] with NH₂Bu^t in CH₂Cl₂ yields yellow crystals of [MoCl₄(NH₂Bu^t)₂]· 2NH₂Bu^t. The structure is shown to consist of both cis and trans isomers of [MoCl₄(NH₂Bu^t)₂] and uncoordinated NH₂Bu^t molecules. Crystal data: triclinic space group, P1, a=11.767(4), b=12.428(4), c= 19.338(5) Å, α=90.40(2), β=93.19(2), γ= 102.20(2)°, V=2759.3(14) Å³, D_calc=1.28 g cm^-3, Z=4. Structure solution and refinement based on 2651 reflections (Mo Kα, λ=0.71073 Å, F_o≥ 6σ(F_o)) converged at R=0.058.

Original language	English (US)
Pages (from-to)	43-46
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	168
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)88015-9
State	Published - Feb 1 1990
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{51769f661b2242bd80837838afa75a37,

title = "Synthesis and structural characterization of cis and trans [MoCl4(H2NBut)2]",

abstract = "The reaction of [MoCl4(PPh3)2] with NH2But in CH2Cl2 yields yellow crystals of [MoCl4(NH2But)2]· 2NH2But. The structure is shown to consist of both cis and trans isomers of [MoCl4(NH2But)2] and uncoordinated NH2But molecules. Crystal data: triclinic space group, P1, a=11.767(4), b=12.428(4), c= 19.338(5) {\AA}, α=90.40(2), β=93.19(2), γ= 102.20(2)°, V=2759.3(14) {\AA}3, Dcalc=1.28 g cm-3, Z=4. Structure solution and refinement based on 2651 reflections (Mo Kα, λ=0.71073 {\AA}, Fo≥ 6σ(Fo)) converged at R=0.058.",

author = "Shuncheng Liu and Jon Zubieta",

year = "1990",

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doi = "10.1016/S0020-1693(00)88015-9",

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TY - JOUR

T1 - Synthesis and structural characterization of cis and trans [MoCl4(H2NBut)2]

AU - Liu, Shuncheng

AU - Zubieta, Jon

PY - 1990/2/1

Y1 - 1990/2/1

N2 - The reaction of [MoCl4(PPh3)2] with NH2But in CH2Cl2 yields yellow crystals of [MoCl4(NH2But)2]· 2NH2But. The structure is shown to consist of both cis and trans isomers of [MoCl4(NH2But)2] and uncoordinated NH2But molecules. Crystal data: triclinic space group, P1, a=11.767(4), b=12.428(4), c= 19.338(5) Å, α=90.40(2), β=93.19(2), γ= 102.20(2)°, V=2759.3(14) Å3, Dcalc=1.28 g cm-3, Z=4. Structure solution and refinement based on 2651 reflections (Mo Kα, λ=0.71073 Å, Fo≥ 6σ(Fo)) converged at R=0.058.

AB - The reaction of [MoCl4(PPh3)2] with NH2But in CH2Cl2 yields yellow crystals of [MoCl4(NH2But)2]· 2NH2But. The structure is shown to consist of both cis and trans isomers of [MoCl4(NH2But)2] and uncoordinated NH2But molecules. Crystal data: triclinic space group, P1, a=11.767(4), b=12.428(4), c= 19.338(5) Å, α=90.40(2), β=93.19(2), γ= 102.20(2)°, V=2759.3(14) Å3, Dcalc=1.28 g cm-3, Z=4. Structure solution and refinement based on 2651 reflections (Mo Kα, λ=0.71073 Å, Fo≥ 6σ(Fo)) converged at R=0.058.

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ER -

Synthesis and structural characterization of cis and trans [MoCl₄(H₂NBu^t)₂]

Abstract

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