Synthesis and structural characterization of cis and trans [MoCl4(H2NBut)2]

Shuncheng Liu, Jon Zubieta

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

The reaction of [MoCl4(PPh3)2] with NH2But in CH2Cl2 yields yellow crystals of [MoCl4(NH2But)2]· 2NH2But. The structure is shown to consist of both cis and trans isomers of [MoCl4(NH2But)2] and uncoordinated NH2But molecules. Crystal data: triclinic space group, P1, a=11.767(4), b=12.428(4), c= 19.338(5) Å, α=90.40(2), β=93.19(2), γ= 102.20(2)°, V=2759.3(14) Å3, Dcalc=1.28 g cm-3, Z=4. Structure solution and refinement based on 2651 reflections (Mo Kα, λ=0.71073 Å, Fo≥ 6σ(Fo)) converged at R=0.058.

Original languageEnglish (US)
Pages (from-to)43-46
Number of pages4
JournalInorganica Chimica Acta
Volume168
Issue number1
DOIs
StatePublished - Feb 1 1990
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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