TY - JOUR
T1 - Synthesis and structural characterization of a binuclear oxomolybdenum(VI) tropolonate complex, (n-Bu4N)2[Mo2O6(trop)2], displaying the novel [MoO2(μ-O)2MoO2]° core
AU - Liu, Shuncheng
AU - Zubieta, Jon
N1 - Funding Information:
work was supported by NSF Zubieta.
Copyright:
Copyright 2014 Elsevier B.V., All rights reserved.
PY - 1988
Y1 - 1988
N2 - Reaction of (n-Bu4N)2[Mo2O7] with tropolone (C7H6O2) in acetonitrile yields (n-Bu4N)2[Mo2O6(trop)2]. The title complex is a unique example of a binuclear oxomolybdenum(VI) species exhibiting the [MoO2(μ-O)2MoO2]° core. Crystal data: monoclinic space group P21/c, a = 10.092(2), b = 14.867(3), c = 17.002(4) Å, β= 93.05(1)°, V = 2547.4(11) Å3, Z = 2, Dcalc. = 1.37 g cm-3; 3764 reflections to give R = 0.035.
AB - Reaction of (n-Bu4N)2[Mo2O7] with tropolone (C7H6O2) in acetonitrile yields (n-Bu4N)2[Mo2O6(trop)2]. The title complex is a unique example of a binuclear oxomolybdenum(VI) species exhibiting the [MoO2(μ-O)2MoO2]° core. Crystal data: monoclinic space group P21/c, a = 10.092(2), b = 14.867(3), c = 17.002(4) Å, β= 93.05(1)°, V = 2547.4(11) Å3, Z = 2, Dcalc. = 1.37 g cm-3; 3764 reflections to give R = 0.035.
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U2 - 10.1016/S0277-5387(00)86405-0
DO - 10.1016/S0277-5387(00)86405-0
M3 - Article
AN - SCOPUS:0008994828
SN - 0277-5387
VL - 7
SP - 1129
EP - 1130
JO - Polyhedron
JF - Polyhedron
IS - 12
ER -