Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo4O 10(O4C6H2)2] 2-, and a comparison with the mononuclear chloranilate complex [MoO2(HO4C6Cl2)(O4C 6Cl2)]1-

Shuncheng Liu; Shahid N. Shaikh; Jon Zubieta

doi:10.1039/C39880001017

Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo₄O ₁₀(O₄C₆H₂)₂] ^2-, and a comparison with the mononuclear chloranilate complex [MoO₂(HO₄C₆Cl₂)(O₄C ₆Cl₂)]^1-

Shuncheng Liu, Shahid N. Shaikh, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

While reaction of the sterically encumbered chloranil group with (Mo ₂O₇)^2- yields the mononuclear species [MoO ₂(L)(LH)]^1- (L = C₆O₄Cl ₂), dihydroxylbenzoquinone under similar conditions yields the tetranuclear cluster [(Mo₂O₅)₂(C ₆H₂O₄)]^2-, a species with magnetically coupled semiquinone ligands.

Original language	English (US)
Pages (from-to)	1017-1019
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39880001017
State	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Liu, S., Shaikh, S. N., & Zubieta, J. (1988). Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo₄O ₁₀(O₄C₆H₂)₂] ^2-, and a comparison with the mononuclear chloranilate complex [MoO₂(HO₄C₆Cl₂)(O₄C ₆Cl₂)]^1-. Journal of the Chemical Society, Chemical Communications, (15), 1017-1019. https://doi.org/10.1039/C39880001017

Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo₄O ₁₀(O₄C₆H₂)₂] ^2-, and a comparison with the mononuclear chloranilate complex [MoO₂(HO₄C₆Cl₂)(O₄C ₆Cl₂)]^1-. / Liu, Shuncheng; Shaikh, Shahid N.; Zubieta, Jon.
In: Journal of the Chemical Society, Chemical Communications, No. 15, 1988, p. 1017-1019.

Research output: Contribution to journal › Article › peer-review

Liu, S, Shaikh, SN & Zubieta, J 1988, 'Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo₄O ₁₀(O₄C₆H₂)₂] ^2-, and a comparison with the mononuclear chloranilate complex [MoO₂(HO₄C₆Cl₂)(O₄C ₆Cl₂)]^1-', Journal of the Chemical Society, Chemical Communications, no. 15, pp. 1017-1019. https://doi.org/10.1039/C39880001017

Liu, Shuncheng ; Shaikh, Shahid N. ; Zubieta, Jon. / Synthesis and structural characterisation of an unusual tetranuclear oxomolybdenum(VI) complex of dihydroxybenzoquinone, [Mo₄O ₁₀(O₄C₆H₂)₂] ^2-, and a comparison with the mononuclear chloranilate complex [MoO₂(HO₄C₆Cl₂)(O₄C ₆Cl₂)]^1-. In: Journal of the Chemical Society, Chemical Communications. 1988 ; No. 15. pp. 1017-1019.

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abstract = "While reaction of the sterically encumbered chloranil group with (Mo 2O7)2- yields the mononuclear species [MoO 2(L)(LH)]1- (L = C6O4Cl 2), dihydroxylbenzoquinone under similar conditions yields the tetranuclear cluster [(Mo2O5)2(C 6H2O4)]2-, a species with magnetically coupled semiquinone ligands.",

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AB - While reaction of the sterically encumbered chloranil group with (Mo 2O7)2- yields the mononuclear species [MoO 2(L)(LH)]1- (L = C6O4Cl 2), dihydroxylbenzoquinone under similar conditions yields the tetranuclear cluster [(Mo2O5)2(C 6H2O4)]2-, a species with magnetically coupled semiquinone ligands.

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