Synthesis and reactivity of novel alkali metal stannides

Thorsten Schollmeier, Ulrich Englich, Roland Fischer, Ingo Prass, Karin Ruhlandt, Markus Schürmann, Frank Uhlig

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Reactivity and side products of reactions of diorganodihydridostannanes (R 2SnH 2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR′ 2Si)R″ 2SnK (R, R′= Me, Ph; R″= , Me, tBu, Ph) 4-9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR′ 2Si) 2SnR″ 2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSn tBu 3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.

Original languageEnglish (US)
Pages (from-to)1462-1470
Number of pages9
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume59
Issue number11-12
StatePublished - Nov 2004

Fingerprint

Alkali Metals
Alkali metal compounds
Potassium
X ray crystallography
Hydrides
Nuclear magnetic resonance spectroscopy
stannane

Keywords

  • Alkali Metal Stannides
  • Preparation
  • Reactivity, Sn and Si NMR Spectroscopy
  • Structure Elucidation

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Schollmeier, T., Englich, U., Fischer, R., Prass, I., Ruhlandt, K., Schürmann, M., & Uhlig, F. (2004). Synthesis and reactivity of novel alkali metal stannides. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 59(11-12), 1462-1470.

Synthesis and reactivity of novel alkali metal stannides. / Schollmeier, Thorsten; Englich, Ulrich; Fischer, Roland; Prass, Ingo; Ruhlandt, Karin; Schürmann, Markus; Uhlig, Frank.

In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 59, No. 11-12, 11.2004, p. 1462-1470.

Research output: Contribution to journalArticle

Schollmeier, T, Englich, U, Fischer, R, Prass, I, Ruhlandt, K, Schürmann, M & Uhlig, F 2004, 'Synthesis and reactivity of novel alkali metal stannides', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 59, no. 11-12, pp. 1462-1470.
Schollmeier, Thorsten ; Englich, Ulrich ; Fischer, Roland ; Prass, Ingo ; Ruhlandt, Karin ; Schürmann, Markus ; Uhlig, Frank. / Synthesis and reactivity of novel alkali metal stannides. In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2004 ; Vol. 59, No. 11-12. pp. 1462-1470.
@article{61784e06b66b44ed92d9dfcaea60a483,
title = "Synthesis and reactivity of novel alkali metal stannides",
abstract = "Reactivity and side products of reactions of diorganodihydridostannanes (R 2SnH 2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR′ 2Si)R″ 2SnK (R, R′= Me, Ph; R″= , Me, tBu, Ph) 4-9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR′ 2Si) 2SnR″ 2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSn tBu 3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.",
keywords = "Alkali Metal Stannides, Preparation, Reactivity, Sn and Si NMR Spectroscopy, Structure Elucidation",
author = "Thorsten Schollmeier and Ulrich Englich and Roland Fischer and Ingo Prass and Karin Ruhlandt and Markus Sch{\"u}rmann and Frank Uhlig",
year = "2004",
month = "11",
language = "English (US)",
volume = "59",
pages = "1462--1470",
journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",
issn = "0932-0776",
publisher = "Verlag der Zeitschrift fur Naturforschung",
number = "11-12",

}

TY - JOUR

T1 - Synthesis and reactivity of novel alkali metal stannides

AU - Schollmeier, Thorsten

AU - Englich, Ulrich

AU - Fischer, Roland

AU - Prass, Ingo

AU - Ruhlandt, Karin

AU - Schürmann, Markus

AU - Uhlig, Frank

PY - 2004/11

Y1 - 2004/11

N2 - Reactivity and side products of reactions of diorganodihydridostannanes (R 2SnH 2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR′ 2Si)R″ 2SnK (R, R′= Me, Ph; R″= , Me, tBu, Ph) 4-9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR′ 2Si) 2SnR″ 2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSn tBu 3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.

AB - Reactivity and side products of reactions of diorganodihydridostannanes (R 2SnH 2, R = Me, nBu, tBu)) with various alkali metal compounds have been discussed. Alternatively, the synthesis and characterization of a family of novel potassium stannides are described as well. The compounds of type (RR′ 2Si)R″ 2SnK (R, R′= Me, Ph; R″= , Me, tBu, Ph) 4-9 were synthesized by reaction of potassium hydride with bis(silyl)stannides ((RR′ 2Si) 2SnR″ 2). All compounds were characterized by multinuclear NMR spectroscopy. In addition, the tri-tert-butyltin compound 3 (LiSn tBu 3) and the unsymmetrical silyl substituted stannane 10 were characterized by X-ray crystallography.

KW - Alkali Metal Stannides

KW - Preparation

KW - Reactivity, Sn and Si NMR Spectroscopy

KW - Structure Elucidation

UR - http://www.scopus.com/inward/record.url?scp=12444333504&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=12444333504&partnerID=8YFLogxK

M3 - Article

VL - 59

SP - 1462

EP - 1470

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

SN - 0932-0776

IS - 11-12

ER -