Synthesis and crystal structure of μ4-oxo-hexa-(μ2-(N,S)-1-methylimidazoline-2-thionato)-tetrazinc(II)

Rosa Castro; JoséA A. García-Vásquez; Jaime Romero; Antonio Sousa; Yuan Da Chang; Jon Zubieta

doi:10.1016/0020-1693(95)04676-Z

Synthesis and crystal structure of μ₄-oxo-hexa-(μ₂-(N,S)-1-methylimidazoline-2-thionato)-tetrazinc(II)

Rosa Castro, JoséA A. García-Vásquez, Jaime Romero, Antonio Sousa, Yuan Da Chang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn₄O(MeImt)₆] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.

Original language	English (US)
Pages (from-to)	143-146
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	237
Issue number	1-2
DOIs	https://doi.org/10.1016/0020-1693(95)04676-Z
State	Published - Sep 1995

Keywords

Crystal structures
Electrochemistry
Heterpcyclic thione complexes
Zinc complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0020-1693(95)04676-Z

Cite this

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title = "Synthesis and crystal structure of μ4-oxo-hexa-(μ2-(N,S)-1-methylimidazoline-2-thionato)-tetrazinc(II)",

abstract = "Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)6] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.",

keywords = "Crystal structures, Electrochemistry, Heterpcyclic thione complexes, Zinc complexes",

author = "Rosa Castro and Garc{\'i}a-V{\'a}squez, {Jos{\'e}A A.} and Jaime Romero and Antonio Sousa and Chang, {Yuan Da} and Jon Zubieta",

year = "1995",

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doi = "10.1016/0020-1693(95)04676-Z",

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pages = "143--146",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Synthesis and crystal structure of μ4-oxo-hexa-(μ2-(N,S)-1-methylimidazoline-2-thionato)-tetrazinc(II)

AU - Castro, Rosa

AU - García-Vásquez, JoséA A.

AU - Romero, Jaime

AU - Sousa, Antonio

AU - Chang, Yuan Da

AU - Zubieta, Jon

PY - 1995/9

Y1 - 1995/9

N2 - Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)6] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.

AB - Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)6] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.

KW - Crystal structures

KW - Electrochemistry

KW - Heterpcyclic thione complexes

KW - Zinc complexes

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