Synthesis and crystal structure of μ4-oxo-hexa-(μ2-(N,S)-1-methylimidazoline-2-thionato)-tetrazinc(II)

Rosa Castro, JoséA A. García-Vásquez, Jaime Romero, Antonio Sousa, Yuan Da Chang, Jon Zubieta

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

Electrochemical oxidation of zinc in a solution of 1-methylimidazoline-2-thione (MeImtH) in acetonitrile, gives [Zn4O(MeImt)6] whose crystal structure has been determined by X-ray diffraction. This compound contains a central oxygen atom tetrahedrally bonded to four zinc atoms, bridged by six 1-methylimidazoline-2-thionato ligands along the edges of the tetrahedron. Each zinc atom exhibits tetrahedral coordination.

Original languageEnglish (US)
Pages (from-to)143-146
Number of pages4
JournalInorganica Chimica Acta
Volume237
Issue number1-2
DOIs
StatePublished - Sep 1995

Keywords

  • Crystal structures
  • Electrochemistry
  • Heterpcyclic thione complexes
  • Zinc complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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