Synthesis and crystal and molecular structure of (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed-valence cluster with the decametallate core geometry

Michael Cavaluzzo, Qin Chen, Jon Zubieta

Research output: Contribution to journalArticle

48 Scopus citations

Abstract

The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.

Original languageEnglish (US)
Pages (from-to)131-133
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number2
DOIs
StatePublished - Dec 1 1993

ASJC Scopus subject areas

  • Molecular Medicine

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