Synthesis and crystal and molecular structure of (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed-valence cluster with the decametallate core geometry

Michael Cavaluzzo; Qin Chen; Jon Zubieta

doi:10.1039/C39930000131

Synthesis and crystal and molecular structure of (Et₄N) ₂[Mn₁₀O₂Cl₈{(OCH₂) ₃CMe}₆]·4MeOH·2H₂O, a Mn ^II,III mixed-valence cluster with the decametallate core geometry

Michael Cavaluzzo, Qin Chen, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

The reaction of (Et₄N)₂MnCl₄ with MeC(CH₂OH)₃ in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et₄N) ₂[Mn₁₀O₂Cl₈{(OCH₂) ₃CMe}₆]·4MeOH·2H₂O, a Mn ^II,III mixed valence species exhibiting the decametallate core geometry, {M₁₀O₂L₂₆}.

Original language	English (US)
Pages (from-to)	131-133
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39930000131
State	Published - Dec 1 1993

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Molecular Medicine

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Synthesis and crystal and molecular structure of (Et₄N) ₂[Mn₁₀O₂Cl₈{(OCH₂) ₃CMe}₆]·4MeOH·2H₂O, a Mn ^II,III mixed-valence cluster with the decametallate core geometry. / Cavaluzzo, Michael; Chen, Qin; Zubieta, Jon.

In: Journal of the Chemical Society, Chemical Communications, No. 2, 01.12.1993, p. 131-133.

Research output: Contribution to journal › Article › peer-review

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title = "Synthesis and crystal and molecular structure of (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed-valence cluster with the decametallate core geometry",

abstract = "The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.",

author = "Michael Cavaluzzo and Qin Chen and Jon Zubieta",

year = "1993",

month = dec,

day = "1",

doi = "10.1039/C39930000131",

language = "English (US)",

pages = "131--133",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Synthesis and crystal and molecular structure of (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed-valence cluster with the decametallate core geometry

AU - Cavaluzzo, Michael

AU - Chen, Qin

AU - Zubieta, Jon

PY - 1993/12/1

Y1 - 1993/12/1

N2 - The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.

AB - The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N) 2[Mn10O2Cl8{(OCH2) 3CMe}6]·4MeOH·2H2O, a Mn II,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.

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DO - 10.1039/C39930000131

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ER -

Synthesis and crystal and molecular structure of (Et₄N) ₂[Mn₁₀O₂Cl₈{(OCH₂) ₃CMe}₆]·4MeOH·2H₂O, a Mn ^II,III mixed-valence cluster with the decametallate core geometry

Abstract

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