TY - JOUR
T1 - Synthesis and characterization of zinc and cadmium compounds with arenephosphinothiol ligands.
AU - Pérez-Lourido, Paulo
AU - Romero, Jaime
AU - García-Vázquez, José A.
AU - Sousa, Antonio
AU - Maresca, Kevin P.
AU - Zubieta, Jon
PY - 1999
Y1 - 1999
N2 - The electrochemical oxidation of a metallic anode (zinc or cadmium) in an acetonitrile solution of a series of arenephosphinothiol ligands, 2-(Ph2P)C6H4SH, 2-(Ph2P)-6-(Me3Si)C6H3SH, 2-(Ph2PO)-6-(Me3Si)C6H3SH, and PhP-(C6H4SH-2)2 [abbreviated RP-CSH)x, x = 1 or 2], affords [M(RP-S)2] and [M(RP-S2)], M = Zn, Cd. Adducts of several of these compounds with 1,10-phenanthroline and 2,2′-bipyridine have also been obtained by addition of these coligands to the electrolysis phase. The compounds obtained have been characterized by microanalysis, IR, UV-visible, FAB spectrometry and 1H, 31P NMR spectroscopic studies.
AB - The electrochemical oxidation of a metallic anode (zinc or cadmium) in an acetonitrile solution of a series of arenephosphinothiol ligands, 2-(Ph2P)C6H4SH, 2-(Ph2P)-6-(Me3Si)C6H3SH, 2-(Ph2PO)-6-(Me3Si)C6H3SH, and PhP-(C6H4SH-2)2 [abbreviated RP-CSH)x, x = 1 or 2], affords [M(RP-S)2] and [M(RP-S2)], M = Zn, Cd. Adducts of several of these compounds with 1,10-phenanthroline and 2,2′-bipyridine have also been obtained by addition of these coligands to the electrolysis phase. The compounds obtained have been characterized by microanalysis, IR, UV-visible, FAB spectrometry and 1H, 31P NMR spectroscopic studies.
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U2 - 10.1021/ic981405b
DO - 10.1021/ic981405b
M3 - Article
AN - SCOPUS:0000683860
SN - 0020-1669
VL - 38
SP - 3709
EP - 3715
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 16
ER -