Synthesis and characterization of zinc and cadmium compounds with arenephosphinothiol ligands.

Paulo Pérez-Lourido, Jaime Romero, José A. García-Vázquez, Antonio Sousa, Kevin P. Maresca, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

33 Scopus citations

Abstract

The electrochemical oxidation of a metallic anode (zinc or cadmium) in an acetonitrile solution of a series of arenephosphinothiol ligands, 2-(Ph2P)C6H4SH, 2-(Ph2P)-6-(Me3Si)C6H3SH, 2-(Ph2PO)-6-(Me3Si)C6H3SH, and PhP-(C6H4SH-2)2 [abbreviated RP-CSH)x, x = 1 or 2], affords [M(RP-S)2] and [M(RP-S2)], M = Zn, Cd. Adducts of several of these compounds with 1,10-phenanthroline and 2,2′-bipyridine have also been obtained by addition of these coligands to the electrolysis phase. The compounds obtained have been characterized by microanalysis, IR, UV-visible, FAB spectrometry and 1H, 31P NMR spectroscopic studies.

Original languageEnglish (US)
Pages (from-to)3709-3715
Number of pages7
JournalInorganic Chemistry
Volume38
Issue number16
DOIs
StatePublished - 1999

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Synthesis and characterization of zinc and cadmium compounds with arenephosphinothiol ligands.'. Together they form a unique fingerprint.

Cite this