TY - JOUR
T1 - Synthesis and characterization of uranyl thiolate complexes. Crystal and molecular structures of [Me4N] [UO2(NO3)2(C5H4NS)] and [C16H25N2S2SI2] [UO2(NO3)2(C8H12NSSi)]
AU - Rose, David J.
AU - Chen, Qin
AU - Zubieta, Jon
PY - 1998/2/3
Y1 - 1998/2/3
N2 - The preparations of two monomeric uranyl thiolate compounds are presented, [Me4N][UO2(NO3)2(C5H 4NS)] (4) and [C16H25N2S2Si2] [UO2(NO3)2(C8H12NSSi)] (5). Crystal data: 4, C9H16N4O8SU, orthorhombic, P212121, a = 8.553(2), b = 13.921(2), c= 14.895(2) Å, V = 1773.7(9) Å3, Z = 4, 1356 reflections, R = 0.0463. 5, C24H37N5O8S3Si 3U, monoclinic, P21/c, a = 11.925(2), b = 27.429(5), c = 11.462(2) Å, β = 97.33(3)°, V=3718(2) Å3, Z = 4, 1055 reflections, R = 0.0518. These are possible precursors to previously reported uranyl-peroxo and -oxo thiolate clusters. Attempts at oxo transfer from the clusters to substrates are also discussed.
AB - The preparations of two monomeric uranyl thiolate compounds are presented, [Me4N][UO2(NO3)2(C5H 4NS)] (4) and [C16H25N2S2Si2] [UO2(NO3)2(C8H12NSSi)] (5). Crystal data: 4, C9H16N4O8SU, orthorhombic, P212121, a = 8.553(2), b = 13.921(2), c= 14.895(2) Å, V = 1773.7(9) Å3, Z = 4, 1356 reflections, R = 0.0463. 5, C24H37N5O8S3Si 3U, monoclinic, P21/c, a = 11.925(2), b = 27.429(5), c = 11.462(2) Å, β = 97.33(3)°, V=3718(2) Å3, Z = 4, 1055 reflections, R = 0.0518. These are possible precursors to previously reported uranyl-peroxo and -oxo thiolate clusters. Attempts at oxo transfer from the clusters to substrates are also discussed.
KW - Crystal structures
KW - Thiolate complexes
KW - Uranyl complexes
UR - http://www.scopus.com/inward/record.url?scp=0039993574&partnerID=8YFLogxK
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U2 - 10.1016/S0020-1693(97)05732-0
DO - 10.1016/S0020-1693(97)05732-0
M3 - Article
AN - SCOPUS:0039993574
SN - 0020-1693
VL - 268
SP - 163
EP - 167
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -