TY - JOUR
T1 - Synthesis and characterization of three novel inorganic/organic hybrid materials based on polyoxomolybdate clusters
T2 - An investigation into the structural consequences of steric effect of the organoimine ligands
AU - Nandini Devi, R.
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by NSF grant, CHE9987471.
PY - 2002/4/17
Y1 - 2002/4/17
N2 - Hydrothermal means have been employed in isolating three new compounds, [Cu2Mo4O13(C5H6N 2)2·3H2O] (1), [Cu2Mo4O13(C6H8N 2)2] (2) and [CuMo6O19(C18H24N2)] (3) from mixtures of CuNO3/CuSO4, the corresponding ligands (methylpyrazine, dimethylpyrimidine and ditertiarybutyl-2,2′-bipyridine) and MoO3 at temperatures from 120 to 160°C. The structures of these compounds range from three-dimensional in the case of 1 to 'zero-dimensional' or molecular in the case of 3 in accordance with the extent of steric hindrance presented by the ligand.
AB - Hydrothermal means have been employed in isolating three new compounds, [Cu2Mo4O13(C5H6N 2)2·3H2O] (1), [Cu2Mo4O13(C6H8N 2)2] (2) and [CuMo6O19(C18H24N2)] (3) from mixtures of CuNO3/CuSO4, the corresponding ligands (methylpyrazine, dimethylpyrimidine and ditertiarybutyl-2,2′-bipyridine) and MoO3 at temperatures from 120 to 160°C. The structures of these compounds range from three-dimensional in the case of 1 to 'zero-dimensional' or molecular in the case of 3 in accordance with the extent of steric hindrance presented by the ligand.
KW - Hydrothermal synthesis
KW - Organic-inorganic hybrid materials
KW - Polyoxomolybdate cluster
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U2 - 10.1016/S0020-1693(02)00699-0
DO - 10.1016/S0020-1693(02)00699-0
M3 - Article
AN - SCOPUS:0037123189
SN - 0020-1693
VL - 332
SP - 72
EP - 78
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -