Synthesis and Characterization of Thiolato Complexes with Two‐Coordinate Iron(II)

Jeffrey J. Ellison, Karin Ruhlandt‐Senge, Philip P. Power

Research output: Contribution to journalArticle

103 Scopus citations

Abstract

Coordination number two, ten valence electrons, and highly bent ligands owing to the weak secondary interactions with ortho mesityl substituents—these characteristic features are present in one (shown on the right) of the first two thiolato complexes with a two‐coordinate FeII center. Low coordinate iron centers of this kind bound to sulfur are of particular interest in light of the crystal structure of the FeMo cofactor of nitrogenase. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1178-1180
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume33
Issue number11
DOIs
StatePublished - Jun 22 1994
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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