TY - JOUR
T1 - Synthesis and Characterization of Thiolato Complexes with Two‐Coordinate Iron(II)
AU - Ellison, Jeffrey J.
AU - Ruhlandt‐Senge, Karin
AU - Power, Philip P.
PY - 1994/6/22
Y1 - 1994/6/22
N2 - Coordination number two, ten valence electrons, and highly bent ligands owing to the weak secondary interactions with ortho mesityl substituents—these characteristic features are present in one (shown on the right) of the first two thiolato complexes with a two‐coordinate FeII center. Low coordinate iron centers of this kind bound to sulfur are of particular interest in light of the crystal structure of the FeMo cofactor of nitrogenase. (Figure Presented.)
AB - Coordination number two, ten valence electrons, and highly bent ligands owing to the weak secondary interactions with ortho mesityl substituents—these characteristic features are present in one (shown on the right) of the first two thiolato complexes with a two‐coordinate FeII center. Low coordinate iron centers of this kind bound to sulfur are of particular interest in light of the crystal structure of the FeMo cofactor of nitrogenase. (Figure Presented.)
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U2 - 10.1002/anie.199411781
DO - 10.1002/anie.199411781
M3 - Article
AN - SCOPUS:33751127094
SN - 0570-0833
VL - 33
SP - 1178
EP - 1180
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 11
ER -