Synthesis and characterization of the monomeric three-coordinate indium thiolate and selenolate complexes in[E(2,4,6-t-Bu3C6H2)]3 (E = S, Se)

Karin Ruhlandt, P. P. Power

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Abstract

The synthesis and characterization of the monomeric neutral three-coordinate indium thiolate and selenolate derivatives In[S(2,4)6-t-Bu3C6H2)]3 (1) and In[Se(2,4,6-t-Bu3C6H2)] 3·2PhMe(2)are described. Compound 1 was synthesized by the reaction of In[N(SiMe3)2]3 with 3 equiv of HS(2,4,6-t-Bu3C6H2) in toluene whereas 2 was obtained by the reaction of InEt3 with 3 equiv of HSe(2,4,6-t-Bu3C6H2) in the same solvent. The compounds display an essentially planar trigonal coordination at the indium atom with an average In-S bond length of 2.398(6) Å and an average In-Se distance of 2.505(3) Å. The compounds were characterized by IR and 1H NMR (77Se NMR in the case of 2) spectroscopy and by X-ray crystallography. Crystal data with Mo Kα (λ = 0.710 69 Å) at 130 K: 1, a = 10.244(3) Å, b = 26.31(2) Å, c = 20.070(10) Å, β = 90.74°, V = 5409(5) Å3, Z = 4, space group P21/n, 4834 (I > 2.5σ(I)) data, R = 0.061; 2, a = 14.538(4) Å, b = 14.796(3) Å, c = 16.701(5) Å, α = 85.65(2)°, β = 83.60(2)°, γ = 61.64(2)°, V = 3140.4(13) Å3, Z = 2, space group P1, 8415 (I > 3σ(I)) data, R = 0.049.

Original languageEnglish (US)
Pages (from-to)3478-3481
Number of pages4
JournalInorganic Chemistry
Volume32
Issue number16
StatePublished - 1993
Externally publishedYes

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Indium
indium
Nuclear magnetic resonance
nuclear magnetic resonance
X ray crystallography
Toluene
Bond length
synthesis
crystallography
toluene
Spectroscopy
Derivatives
Atoms
Crystals
spectroscopy
crystals
atoms
x rays
HS 3

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

@article{433fe15098ee4752bd897d35d67f2a52,
title = "Synthesis and characterization of the monomeric three-coordinate indium thiolate and selenolate complexes in[E(2,4,6-t-Bu3C6H2)]3 (E = S, Se)",
abstract = "The synthesis and characterization of the monomeric neutral three-coordinate indium thiolate and selenolate derivatives In[S(2,4)6-t-Bu3C6H2)]3 (1) and In[Se(2,4,6-t-Bu3C6H2)] 3·2PhMe(2)are described. Compound 1 was synthesized by the reaction of In[N(SiMe3)2]3 with 3 equiv of HS(2,4,6-t-Bu3C6H2) in toluene whereas 2 was obtained by the reaction of InEt3 with 3 equiv of HSe(2,4,6-t-Bu3C6H2) in the same solvent. The compounds display an essentially planar trigonal coordination at the indium atom with an average In-S bond length of 2.398(6) {\AA} and an average In-Se distance of 2.505(3) {\AA}. The compounds were characterized by IR and 1H NMR (77Se NMR in the case of 2) spectroscopy and by X-ray crystallography. Crystal data with Mo Kα (λ = 0.710 69 {\AA}) at 130 K: 1, a = 10.244(3) {\AA}, b = 26.31(2) {\AA}, c = 20.070(10) {\AA}, β = 90.74°, V = 5409(5) {\AA}3, Z = 4, space group P21/n, 4834 (I > 2.5σ(I)) data, R = 0.061; 2, a = 14.538(4) {\AA}, b = 14.796(3) {\AA}, c = 16.701(5) {\AA}, α = 85.65(2)°, β = 83.60(2)°, γ = 61.64(2)°, V = 3140.4(13) {\AA}3, Z = 2, space group P1, 8415 (I > 3σ(I)) data, R = 0.049.",
author = "Karin Ruhlandt and Power, {P. P.}",
year = "1993",
language = "English (US)",
volume = "32",
pages = "3478--3481",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "16",

}

TY - JOUR

T1 - Synthesis and characterization of the monomeric three-coordinate indium thiolate and selenolate complexes in[E(2,4,6-t-Bu3C6H2)]3 (E = S, Se)

AU - Ruhlandt, Karin

AU - Power, P. P.

PY - 1993

Y1 - 1993

N2 - The synthesis and characterization of the monomeric neutral three-coordinate indium thiolate and selenolate derivatives In[S(2,4)6-t-Bu3C6H2)]3 (1) and In[Se(2,4,6-t-Bu3C6H2)] 3·2PhMe(2)are described. Compound 1 was synthesized by the reaction of In[N(SiMe3)2]3 with 3 equiv of HS(2,4,6-t-Bu3C6H2) in toluene whereas 2 was obtained by the reaction of InEt3 with 3 equiv of HSe(2,4,6-t-Bu3C6H2) in the same solvent. The compounds display an essentially planar trigonal coordination at the indium atom with an average In-S bond length of 2.398(6) Å and an average In-Se distance of 2.505(3) Å. The compounds were characterized by IR and 1H NMR (77Se NMR in the case of 2) spectroscopy and by X-ray crystallography. Crystal data with Mo Kα (λ = 0.710 69 Å) at 130 K: 1, a = 10.244(3) Å, b = 26.31(2) Å, c = 20.070(10) Å, β = 90.74°, V = 5409(5) Å3, Z = 4, space group P21/n, 4834 (I > 2.5σ(I)) data, R = 0.061; 2, a = 14.538(4) Å, b = 14.796(3) Å, c = 16.701(5) Å, α = 85.65(2)°, β = 83.60(2)°, γ = 61.64(2)°, V = 3140.4(13) Å3, Z = 2, space group P1, 8415 (I > 3σ(I)) data, R = 0.049.

AB - The synthesis and characterization of the monomeric neutral three-coordinate indium thiolate and selenolate derivatives In[S(2,4)6-t-Bu3C6H2)]3 (1) and In[Se(2,4,6-t-Bu3C6H2)] 3·2PhMe(2)are described. Compound 1 was synthesized by the reaction of In[N(SiMe3)2]3 with 3 equiv of HS(2,4,6-t-Bu3C6H2) in toluene whereas 2 was obtained by the reaction of InEt3 with 3 equiv of HSe(2,4,6-t-Bu3C6H2) in the same solvent. The compounds display an essentially planar trigonal coordination at the indium atom with an average In-S bond length of 2.398(6) Å and an average In-Se distance of 2.505(3) Å. The compounds were characterized by IR and 1H NMR (77Se NMR in the case of 2) spectroscopy and by X-ray crystallography. Crystal data with Mo Kα (λ = 0.710 69 Å) at 130 K: 1, a = 10.244(3) Å, b = 26.31(2) Å, c = 20.070(10) Å, β = 90.74°, V = 5409(5) Å3, Z = 4, space group P21/n, 4834 (I > 2.5σ(I)) data, R = 0.061; 2, a = 14.538(4) Å, b = 14.796(3) Å, c = 16.701(5) Å, α = 85.65(2)°, β = 83.60(2)°, γ = 61.64(2)°, V = 3140.4(13) Å3, Z = 2, space group P1, 8415 (I > 3σ(I)) data, R = 0.049.

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JF - Inorganic Chemistry

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