Abstract
Potassium hydride reacts with HSC6H2Pri3-2,4,6 (HSR) in THF or thf-tmen (tmen = N,N,N′,N′-tetramethylethylenediamine) to afford the first discrete, hexameric potassium thiolates [{K(SR)}2{K(thf)(SR)}2{K(thf)2(SR)} 2] 3 and [{K(SR)}2{K(thf)(SR)}2{K(tmen)(SR)}2] 4·thf, exhibiting an unusual box-shaped structure with three different coordination spheres for the three independent potassium atoms.
Original language | English (US) |
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Pages (from-to) | 147-148 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 2 |
DOIs | |
State | Published - 1996 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- General Chemistry
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry