Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane

Pei Ma, Tiffany M.Smith Pellizzeri, Jon A Zubieta, James T Spencer

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.]

Original languageEnglish (US)
JournalJournal of Chemical Crystallography
DOIs
StateAccepted/In press - Jan 1 2018

Fingerprint

Rhenium
rhenium
Carbon Monoxide
tetrahydrofuran
Manganese Compounds
manganese compounds
Derivatives
diethyl ether
synthesis
Ether
Crystal structure
crystal structure
hydronium ion
1,4-dioxane

Keywords

  • Functionalization
  • Metallaborane
  • Metalladecaborane
  • Oxonium derivatives
  • Rhenium

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane. / Ma, Pei; Pellizzeri, Tiffany M.Smith; Zubieta, Jon A; Spencer, James T.

In: Journal of Chemical Crystallography, 01.01.2018.

Research output: Contribution to journalArticle

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abstract = "Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) {\AA}, b = 9.6971(6) {\AA}, c = 12.5762(8) {\AA}, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.]",
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AU - Ma, Pei

AU - Pellizzeri, Tiffany M.Smith

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N2 - Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.]

AB - Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.]

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