Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane

Pei Ma; Tiffany M.Smith Pellizzeri; Jon Zubieta; James T. Spencer

doi:10.1007/s10870-018-0749-8

Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane

Pei Ma, Tiffany M.Smith Pellizzeri, Jon Zubieta, James T. Spencer

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)₃B₉H₁₃][NMe₄] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH₂)₄O-nido-6-Re(CO)₃B₉H₁₂] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.].

Original language	English (US)
Pages (from-to)	14-20
Number of pages	7
Journal	Journal of Chemical Crystallography
Volume	50
Issue number	1
DOIs	https://doi.org/10.1007/s10870-018-0749-8
State	Published - Mar 1 2020

Keywords

Functionalization
Metallaborane
Metalladecaborane
Oxonium derivatives
Rhenium

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

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10.1007/s10870-018-0749-8

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title = "Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane",

abstract = "Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) {\AA}, b = 9.6971(6) {\AA}, c = 12.5762(8) {\AA}, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.].",

keywords = "Functionalization, Metallaborane, Metalladecaborane, Oxonium derivatives, Rhenium",

author = "Pei Ma and Pellizzeri, {Tiffany M.Smith} and Jon Zubieta and Spencer, {James T.}",

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year = "2020",

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T1 - Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane

AU - Ma, Pei

AU - Pellizzeri, Tiffany M.Smith

AU - Zubieta, Jon

AU - Spencer, James T.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.].

AB - Abstract: The synthesis, characterization, and reaction mechanism of a series of oxonium derivatives of the rhenium containing metalladecaborane [nido-6-Re(CO)3B9H13][NMe4] are reported herein. The oxonium species were synthesized using tetrahydrofuran, 1,4-dioxane, and diethyl ether. The crystal structure of the tetrahydrofuran derivative [2-(CH2)4O-nido-6-Re(CO)3B9H12] was determined and compared to the isostructural manganese compound. The title compound crystallizes in the Triclinic space group P-1 with (a = 7.0835(5) Å, b = 9.6971(6) Å, c = 12.5762(8) Å, α = 73.5750(10)º, β = 75.5520(10)º, γ = 87.061(2)º, volume = 802.22(9), Z = 2). This facile functionalization strategy will facilitate future investigations of rhenium containing metallaboranes and metallacarboranes. Graphical Abstract: [Figure not available: see fulltext.].

KW - Functionalization

KW - Metallaborane

KW - Metalladecaborane

KW - Oxonium derivatives

KW - Rhenium

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Synthesis and Characterization of Oxonium Functionalized Rhenium Metallaborane

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