Synthesis and characterization of oxomolybdate clusters containing coordinatively bound organo-diazenido units: the crystal and molecular structure of the hexanuclear diazenido-oxomolybdate, (NBun4)3[Mo6O18(N2C6H5)]

Tze Chen Hsieh; Jon A. Zubieta

doi:10.1016/S0277-5387(00)84576-3

Synthesis and characterization of oxomolybdate clusters containing coordinatively bound organo-diazenido units: the crystal and molecular structure of the hexanuclear diazenido-oxomolybdate, (NBuⁿ₄)₃[Mo₆O₁₈(N₂C₆H₅)]

Tze Chen Hsieh, Jon A. Zubieta

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

(NBuⁿ₄)₃[Mo₆O₁₈(N₂C₆H₅)] has been obtained by treating (NBuⁿ₄)₂[Mo₆O₁₉] with an equivalent amount of phenylhdyrazine in benzene. X-ray crsytallography reveals the identity of the deep red crystalline material as a polymolybdate species incorporating a coordinatively bound organo-diazenido unit. The anion [Mo₆O₁₈(N₂C₆H₅)]^3- is structurally similar to the precursor [Mo₆O₁₉]^2-, with the terminally bound phenyldiazenido group replacing a terminal oxo unit of the hexamolybdate moiety. (NBuⁿ₄)₃[Mo₆O₁₈(N₂C₆H₅)] crystallizes in the orthorhombic space group Pmcn with a = 17.162(3) Å, b = 17.577(3) Å, c = 23.860(4) Å, V = 7197.7(8) Å³, Z = 4, and D_c = 1.56 g cm^-3 [μ = 10.60 cm^-1, Mo-K_α (λ = 0.71069 Å)]. Solution and refinement based on 2118 reflections with I_o ≥ 3σ(I_o gave a final reisdual of 0.080.

Original language	English (US)
Pages (from-to)	1655-1657
Number of pages	3
Journal	Polyhedron
Volume	5
Issue number	10
DOIs	https://doi.org/10.1016/S0277-5387(00)84576-3
State	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Synthesis and characterization of oxomolybdate clusters containing coordinatively bound organo-diazenido units: the crystal and molecular structure of the hexanuclear diazenido-oxomolybdate, (NBuⁿ₄)₃[Mo₆O₁₈(N₂C₆H₅)]. / Hsieh, Tze Chen; Zubieta, Jon A.
In: Polyhedron, Vol. 5, No. 10, 1986, p. 1655-1657.

Research output: Contribution to journal › Article › peer-review

@article{229e53b53d444c9a9156bc552dc431b7,

title = "Synthesis and characterization of oxomolybdate clusters containing coordinatively bound organo-diazenido units: the crystal and molecular structure of the hexanuclear diazenido-oxomolybdate, (NBun4)3[Mo6O18(N2C6H5)]",

abstract = "(NBun4)3[Mo6O18(N2C6H5)] has been obtained by treating (NBun4)2[Mo6O19] with an equivalent amount of phenylhdyrazine in benzene. X-ray crsytallography reveals the identity of the deep red crystalline material as a polymolybdate species incorporating a coordinatively bound organo-diazenido unit. The anion [Mo6O18(N2C6H5)]3- is structurally similar to the precursor [Mo6O19]2-, with the terminally bound phenyldiazenido group replacing a terminal oxo unit of the hexamolybdate moiety. (NBun4)3[Mo6O18(N2C6H5)] crystallizes in the orthorhombic space group Pmcn with a = 17.162(3) {\AA}, b = 17.577(3) {\AA}, c = 23.860(4) {\AA}, V = 7197.7(8) {\AA}3, Z = 4, and Dc = 1.56 g cm-3 [μ = 10.60 cm-1, Mo-Kα (λ = 0.71069 {\AA})]. Solution and refinement based on 2118 reflections with Io ≥ 3σ(Io gave a final reisdual of 0.080.",

author = "Hsieh, {Tze Chen} and Zubieta, {Jon A.}",

year = "1986",

doi = "10.1016/S0277-5387(00)84576-3",

language = "English (US)",

volume = "5",

pages = "1655--1657",

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TY - JOUR

T1 - Synthesis and characterization of oxomolybdate clusters containing coordinatively bound organo-diazenido units

T2 - the crystal and molecular structure of the hexanuclear diazenido-oxomolybdate, (NBun4)3[Mo6O18(N2C6H5)]

AU - Hsieh, Tze Chen

AU - Zubieta, Jon A.

PY - 1986

Y1 - 1986

N2 - (NBun4)3[Mo6O18(N2C6H5)] has been obtained by treating (NBun4)2[Mo6O19] with an equivalent amount of phenylhdyrazine in benzene. X-ray crsytallography reveals the identity of the deep red crystalline material as a polymolybdate species incorporating a coordinatively bound organo-diazenido unit. The anion [Mo6O18(N2C6H5)]3- is structurally similar to the precursor [Mo6O19]2-, with the terminally bound phenyldiazenido group replacing a terminal oxo unit of the hexamolybdate moiety. (NBun4)3[Mo6O18(N2C6H5)] crystallizes in the orthorhombic space group Pmcn with a = 17.162(3) Å, b = 17.577(3) Å, c = 23.860(4) Å, V = 7197.7(8) Å3, Z = 4, and Dc = 1.56 g cm-3 [μ = 10.60 cm-1, Mo-Kα (λ = 0.71069 Å)]. Solution and refinement based on 2118 reflections with Io ≥ 3σ(Io gave a final reisdual of 0.080.

AB - (NBun4)3[Mo6O18(N2C6H5)] has been obtained by treating (NBun4)2[Mo6O19] with an equivalent amount of phenylhdyrazine in benzene. X-ray crsytallography reveals the identity of the deep red crystalline material as a polymolybdate species incorporating a coordinatively bound organo-diazenido unit. The anion [Mo6O18(N2C6H5)]3- is structurally similar to the precursor [Mo6O19]2-, with the terminally bound phenyldiazenido group replacing a terminal oxo unit of the hexamolybdate moiety. (NBun4)3[Mo6O18(N2C6H5)] crystallizes in the orthorhombic space group Pmcn with a = 17.162(3) Å, b = 17.577(3) Å, c = 23.860(4) Å, V = 7197.7(8) Å3, Z = 4, and Dc = 1.56 g cm-3 [μ = 10.60 cm-1, Mo-Kα (λ = 0.71069 Å)]. Solution and refinement based on 2118 reflections with Io ≥ 3σ(Io gave a final reisdual of 0.080.

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