Synthesis and characterization of oxomolybdate clusters containing co-ordinatively bound diazenido units. The crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(NBu 4)2[Mo8O20(NNPh)6]

Tze Chen Hsieh; Jon Zubieta

doi:10.1039/c39850001749

Synthesis and characterization of oxomolybdate clusters containing co-ordinatively bound diazenido units. The crystal and molecular structure of the octanuclear oxomolybdate (NHEt₃)₂(NBu ₄)₂[Mo₈O₂₀(NNPh)₆]

Tze Chen Hsieh, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Treatment of α-(NR₄)₄[Mo₈O ₂₆] with an excess of phenylhydrazine in ethanol and fractional crystallization yielded a tetranuclear species, [Mo₄O ₈(OEt)₂(NNPh)₄]^2-, with bridging ethoxy groups, and an octanuclear complex, [Mo₈O₂₀(NNPh) ₆]^4-, structurally related to the α-[Mo ₈O₂₆]^4- precursor, as determined by X-ray crystallography; the structure of the Mo₈ precursor is reported.

Original language	English (US)
Pages (from-to)	1749-1750
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/c39850001749
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Synthesis and characterization of oxomolybdate clusters containing co-ordinatively bound diazenido units. The crystal and molecular structure of the octanuclear oxomolybdate (NHEt₃)₂(NBu ₄)₂[Mo₈O₂₀(NNPh)₆]. / Hsieh, Tze Chen; Zubieta, Jon.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1985, p. 1749-1750.

Research output: Contribution to journal › Article › peer-review

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abstract = "Treatment of α-(NR4)4[Mo8O 26] with an excess of phenylhydrazine in ethanol and fractional crystallization yielded a tetranuclear species, [Mo4O 8(OEt)2(NNPh)4]2-, with bridging ethoxy groups, and an octanuclear complex, [Mo8O20(NNPh) 6]4-, structurally related to the α-[Mo 8O26]4- precursor, as determined by X-ray crystallography; the structure of the Mo8 precursor is reported.",

author = "Hsieh, {Tze Chen} and Jon Zubieta",

year = "1985",

doi = "10.1039/c39850001749",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Zubieta, Jon

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N2 - Treatment of α-(NR4)4[Mo8O 26] with an excess of phenylhydrazine in ethanol and fractional crystallization yielded a tetranuclear species, [Mo4O 8(OEt)2(NNPh)4]2-, with bridging ethoxy groups, and an octanuclear complex, [Mo8O20(NNPh) 6]4-, structurally related to the α-[Mo 8O26]4- precursor, as determined by X-ray crystallography; the structure of the Mo8 precursor is reported.

AB - Treatment of α-(NR4)4[Mo8O 26] with an excess of phenylhydrazine in ethanol and fractional crystallization yielded a tetranuclear species, [Mo4O 8(OEt)2(NNPh)4]2-, with bridging ethoxy groups, and an octanuclear complex, [Mo8O20(NNPh) 6]4-, structurally related to the α-[Mo 8O26]4- precursor, as determined by X-ray crystallography; the structure of the Mo8 precursor is reported.

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