Synthesis and Characterization of Binuclear Oxo-Vanadium Complexes of Carbon Oxoanion Ligands. Crystal Structures of the Binuclear Vanadium(IV) Complex (NH4)[V2O2(OH)(C4O4)2(H2O)3]·H2O, of the Mixed-Valence Vanadium(V)/Vanadium(IV)-Squarate Species [(n-C4H9)4N][V2O3(C4O4)2(H2O)3]·3H2O and [(C4H9)4N]4[V4O6(C4O4)5(H2O)4]·6H2O, and of the Binuclear Vanadium(IV)-Oxalate Species [V2O2Cl2(C2O4)(CH3OH)4]·2Ph4Cl

M. Ishaque Khan, Yuan Da Chang, Qin Chen, Jose Salta, Young Sook Lee, Charles J. O'Connor, Jon Zubieta

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Dive into the research topics of 'Synthesis and Characterization of Binuclear Oxo-Vanadium Complexes of Carbon Oxoanion Ligands. Crystal Structures of the Binuclear Vanadium(IV) Complex (NH<sub>4</sub>)[V<sub>2</sub>O<sub>2</sub>(OH)(C<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>]·H<sub>2</sub>O, of the Mixed-Valence Vanadium(V)/Vanadium(IV)-Squarate Species [(n-C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N][V<sub>2</sub>O<sub>3</sub>(C<sub>4</sub>O<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>3</sub>]·3H<sub>2</sub>O and [(C<sub>4</sub>H<sub>9</sub>)<sub>4</sub>N]<sub>4</sub>[V<sub>4</sub>O<sub>6</sub>(C<sub>4</sub>O<sub>4</sub>)<sub>5</sub>(H<sub>2</sub>O)<sub>4</sub>]·6H<sub>2</sub>O, and of the Binuclear Vanadium(IV)-Oxalate Species [V<sub>2</sub>O<sub>2</sub>Cl<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)(CH<sub>3</sub>O<sub>H</sub>)<sub>4</sub>]·2Ph<sub>4</sub>Cl'. Together they form a unique fingerprint.

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